Cover Picture: Two Spectroscopies in One: Interference of Circular Dichroism and Raman Optical Activity (Angew. Chem. Int. Ed. 49/2020)
Why this work is in the frame
A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.
Bibliographic record
Abstract
From the time of Louis Pasteur circular polarized light has been finding many applications in chemical analysis and spectroscopy. In their Communication on page 21895, J. Kapitán, Y. Xu, P. Bouř et al. report another modality, interference of Raman optical activity and circular dichroism, occurring during measurements of transition-metal complexes. The chirality of the complex can be detected in the Raman scattering of the solvent; the effect is strong and may find applications in the detection of chiral compounds. From the time of Louis Pasteur circular polarized light has been finding many applications in chemical analysis and spectroscopy. In their Communication on page 21895, J. Kapitán, Y. Xu, P. Bouř et al. report another modality, interference of Raman optical activity and circular dichroism, occurring during measurements of transition-metal complexes. The chirality of the complex can be detected in the Raman scattering of the solvent; the effect is strong and may find applications in the detection of chiral compounds. Imaging Agents Single-Molecule Magnets Polymerization Phosphorus
Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.001 | 0.001 |
| Meta-epidemiology (broad) | 0.001 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.001 | 0.000 |
| Research integrity | 0.001 | 0.001 |
| Insufficient payload (model declined to judge) | 0.008 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it