MétaCan
Menu
Back to cohort
Record W3127696615 · doi:10.1016/j.nme.2021.100928

Influence of nitrogen on deuterium retention in tungsten under sequential and simultaneous irradiation

2021· article· en· W3127696615 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.
fundA Canadian funder is recorded on the work.

Bibliographic record

VenueNuclear Materials and Energy · 2021
Typearticle
Languageen
FieldMaterials Science
TopicFusion materials and technologies
Canadian institutionsUniversity of Toronto
FundersNatural Sciences and Engineering Research Council of Canada
KeywordsX-ray photoelectron spectroscopyIrradiationTungstenDivertorAnalytical Chemistry (journal)DeuteriumNitrogenNeonChemistryArgonImpurityPlasmaMaterials scienceRadiochemistryAtomic physicsNuclear magnetic resonanceTokamakNuclear physics

Abstract

fetched live from OpenAlex

Nitrogen is a candidate for impurity seeding to reduce the edge plasma temperature for ITER’s tungsten divertor. Radiation characteristics and plasma performance are improved with N compared to other candidates neon and argon, however questions remain in terms of how the introduction of N might impact deuterium retention in W. The current study compares the influence of N on D retention in W with sequential (SEQ) and simultaneous (SIM) irradiation of D-3%N at 300–700 K with energies 500 eV/D+ and 1000 eV/N+. Thermal desorption spectroscopy (TDS) is used to measure the D retained, and X-ray photoelectron spectroscopy (XPS) is used to investigate nitride formation at different implantation temperatures. The XPS results show that for the beam composition of this study, the removal of N by D is the dominant interaction, working against N retention in W. Differences found between the N layer with D/N co-bombardment vs. N pre-irradiation might be worth considering when extrapolating sequential experiments to reactor conditions. The observed effect of the N-containing layer on the temperature dependence of deuterium release during TDS supports the XPS findings, suggesting that the phases of the W:N layer produced are different at different temperatures. It is found that SIM irradiation resulted in an overall increase (up to a factor of ∼4) in total D retention compared to SEQ and D-only experiments above 500 K. At 300–500 K, the D retention was not significantly changed by nitrogen pre-, post- or simultaneous irradiation.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.012
Threshold uncertainty score0.428

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.010
GPT teacher head0.208
Teacher spread0.198 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it