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CO <sub>2</sub> electrolysis to multicarbon products in strong acid

2021· article· en· 1,274 citations· W3165555416 on OpenAlex· 10.1126/science.abg6582

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Canadian affiliationAn author listed a Canadian institution. This is the only route the usual frame has.
Canadian funderA Canadian agency funded it. The work may carry no Canadian affiliation at all.

Machine scores (provisional)

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Opus teacher head0.011
GPT teacher head0.260
Teacher spread
0.249 · how far apart the two teachers sit on this one work
Validation status
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Abstract

Potassium helps CO 2 compete in acid Electrochemical reduction of carbon dioxide (CO 2 ) is a promising means of converting this greenhouse gas into valuable fuels and chemicals. However, two competing reactions restrict the efficiency of this process. In base, much of the CO 2 is trapped as carbonate before reduction; in acid, protons outpace CO 2 at catching electrons from the cathode. Huang et al. report that a high dose of potassium ions can help to solve the latter problem. By concentrating potassium ions at the electrode, high selectivity toward CO 2 reduction at high current in acid is possible, which the authors attribute to electrostatic stabilization of the desired adsorbates. Science , abg6582, this issue p. 1074

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The record

Venue
Science
Topic
CO2 Reduction Techniques and Catalysts
Field
Energy
Canadian institutions
University of Toronto
Funders
Australian Research CouncilArgonne National LaboratoryNatural Sciences and Engineering Research Council of CanadaOffice of ScienceOntario Research Foundation
Keywords
ElectrolysisChemistryEnvironmental scienceElectrodeElectrolyte
Has abstract in OpenAlex
yes