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Record W4210407869 · doi:10.1002/app.52183

Hydrothermal aging of polyimide film

2022· article· en· W4210407869 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.
fundA Canadian funder is recorded on the work.

Bibliographic record

VenueJournal of Applied Polymer Science · 2022
Typearticle
Languageen
FieldMaterials Science
TopicSynthesis and properties of polymers
Canadian institutionsUniversity of Alberta
FundersNatural Sciences and Engineering Research Council of Canada
KeywordsPolyimideHydrothermal circulationUltimate tensile strengthMaterials scienceArrhenius plotAccelerated agingFourier transform infrared spectroscopyPyromellitic dianhydridePolymerComposite materialActivation energyChemical engineeringChemistryOrganic chemistry

Abstract

fetched live from OpenAlex

Abstract The hydrothermal aging of a commercial polyimide film, (poly[pyromellitic dianhydride‐co‐4,4′‐oxydianiline]) is investigated, providing further insight into the well‐known loss of properties that can occur for these materials in the presence of moisture. The study involved measuring ATR‐FTIR, ultimate tensile strength, and percent elongation at break, under accelerated hydrothermal aging conditions at three different temperatures (70, 80, and 90°C). ATR‐FTIR data was analyzed using chemometrics in order to identify significant trends that develop upon the accelerated aging conditions. The most dramatic changes were observed for the aging at 90°C. Changes in the ATR‐FTIR spectra for aging at all three temperatures can be attributed to hydrolysis of the imide groups. Ultimate tensile strength was also used to monitor the hydrothermal aging process. This data was used to construct an Arrhenius plot from which an activation energy of 71.8 KJ/mol was determined for the hydrothermal aging process. This value is comparable to that of textiles used in fire protective clothing, suggesting that polyimide is a viable candidate for modeling the degradation of these textiles. This paper also shows the large potential of chemometrics for polymer aging studies as it allows identifying degradation mechanisms from subtle chemical changes in the materials.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.002
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesInsufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.014
Threshold uncertainty score0.998

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0020.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.001
Science and technology studies0.0000.001
Scholarly communication0.0000.000
Open science0.0010.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0030.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.011
GPT teacher head0.223
Teacher spread0.213 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it