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Atomic energy in grain boundaries studied by machine learning

2022· article· en· W4224104393 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.
fundA Canadian funder is recorded on the work.

Bibliographic record

VenuePhysical Review Materials · 2022
Typearticle
Languageen
FieldMaterials Science
TopicMachine Learning in Materials Science
Canadian institutionsUniversity of Manitoba
FundersNatural Sciences and Engineering Research Council of Canada
KeywordsAmorphous solidNanocrystalline materialMaterials scienceLattice (music)Voronoi diagramAtomic radiusGrain boundaryStatistical physicsNanotechnologyCrystallographyPhysicsMathematicsQuantum mechanicsChemistry

Abstract

fetched live from OpenAlex

Grain boundaries (GBs) have been studied for decades, but it remains a challenging task to describe characteristic GB properties by simple structural descriptors, especially at the local atomic level. In this paper, we use the atomic descriptor based on the smooth overlap of atomic positions (SOAP) to study the atomic energy at GBs by using machine learning and propose a route to simplify it. It is found that, compared with conventional local atomic descriptors such as the Voronoi index, excess volume, centrosymmetry, or local entropy, the SOAP vector shows excellent predictive performance for the atomic energy among the 172 Al and 388 Ni coincidence site lattice (CSL) GBs as well as general GBs in the nanocrystalline model. Additionally, we successfully used the datasets of GBs and amorphous models to predict the atomic energy of one another, which proves the similarity between the local atomic environments (LAEs) in GBs and the amorphous state. Furthermore, the distribution of local distortion factors based on the SOAP vector shows the transition in atomic pack ordering from special CSL GBs to general GBs and the amorphous structures. The simplified descriptor we propose can reduce the original SOAP vector from >1000 features to only a few yet still shows the superior predictive performance of the atomic energy at GBs in all cases than the conventional descriptors combined. It is expected that the simplification process can be adapted to study more complex GB behaviors. A simple and efficient descriptor of the LAEs should allow us to have a clearer picture of the structure-property correlation in GBs, which is essential for GB engineering.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.003
metaresearch head score (Gemma)0.001
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow), Insufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.648
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0030.001
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0000.000
Science and technology studies0.0010.000
Scholarly communication0.0000.000
Open science0.0010.001
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0080.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.011
GPT teacher head0.289
Teacher spread0.279 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it