Interface Engineering of NixSy@MnOxHy Nanorods to Efficiently Enhance Overall-Water-Splitting Activity and Stability
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Bibliographic record
Abstract
Highlights Three-dimensional (3D) core‐shell heterostructured Ni x S y @MnO x H y nanorods grown on nickel foam (Ni x S y @MnO x H y /NF) were successfully fabricated via a simple hydrothermal reaction and a subsequent electrodeposition process. The fabricated Ni x S y @MnO x H y /NF shows outstanding bifunctional activity and stability for hydrogen evolution reaction and oxygen evolution reaction, as well as overall‐water‐splitting performance. The main origins are the interface engineering of Ni x S y @MnO x H y , the shell‐protection characteristic of MnO x H y , and the 3D open nanorod structure, which remarkably endow the electrocatalyst with high activity and stability. Abstract Exploring highly active and stable transition metal-based bifunctional electrocatalysts has recently attracted extensive research interests for achieving high inherent activity, abundant exposed active sites, rapid mass transfer, and strong structure stability for overall water splitting. Herein, an interface engineering coupled with shell-protection strategy was applied to construct three-dimensional (3D) core‐shell Ni x S y @MnO x H y heterostructure nanorods grown on nickel foam (Ni x S y @MnO x H y /NF) as a bifunctional electrocatalyst. Ni x S y @MnO x H y /NF was synthesized via a facile hydrothermal reaction followed by an electrodeposition process. The X-ray absorption fine structure spectra reveal that abundant Mn‐S bonds connect the heterostructure interfaces of Ni x S y @MnO x H y , leading to a strong electronic interaction, which improves the intrinsic activities of hydrogen evolution reaction and oxygen evolution reaction (OER). Besides, as an efficient protective shell, the MnO x H y dramatically inhibits the electrochemical corrosion of the electrocatalyst at high current densities, which remarkably enhances the stability at high potentials. Furthermore, the 3D nanorod structure not only exposes enriched active sites, but also accelerates the electrolyte diffusion and bubble desorption. Therefore, Ni x S y @MnO x H y /NF exhibits exceptional bifunctional activity and stability for overall water splitting, with low overpotentials of 326 and 356 mV for OER at 100 and 500 mA cm –2 , respectively, along with high stability of 150 h at 100 mA cm –2 . Furthermore, for overall water splitting, it presents a low cell voltage of 1.529 V at 10 mA cm –2 , accompanied by excellent stability at 100 mA cm –2 for 100 h. This work sheds a light on exploring highly active and stable bifunctional electrocatalysts by the interface engineering coupled with shell-protection strategy.
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Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.001 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.001 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it