Investigation of 3‐aminopropyltrimethoxysilane for direct deposition of thin films containing primary amine groups by open‐air plasma jets
Why this work is in the frame
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Bibliographic record
Abstract
Abstract Open‐air plasma jets are becoming increasingly popular due to easy and affordable large‐scale coating deposition on diverse substrates. However, direct deposition of primary amine groups (NH 2 ), which are attractive as covalent anchor points for molecule grafting, remains challenging. In this study, 3‐aminopropyltrimethoxysilane (APTMS) has been directly polymerized on glass by a plasma jet. Quantification of NH 2 showed that APTMS polymerization and NH 2 degradation were correlated with Yasuda's parameter and that a compromise between NH 2 retention and coating stability is required. Evaporation of APTMS was found to improve surface smoothness and homogeneity but was found to decrease the deposited NH 2 concentration, from 3.7 ± 1.3 NH 2 /nm 2 to three times lower. Results showed that deposited NH 2 could be used as anchor points for polyethylene glycol chain immobilization.
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Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.001 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it