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Record W4283167169 · doi:10.1002/cjce.24495

Using scientific machine learning to develop universal differential equation for multicomponent adsorption separation systems

2022· article· en· W4283167169 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

venuePublished in a venue whose home country is Canada.
no affNo Canadian affiliation: this work is invisible to an affiliation-only frame.
No Canadian affiliation. An affiliation-only frame, the usual design, would never have seen this work. It is one of the works that make the case for inverting the frame.

Bibliographic record

VenueThe Canadian Journal of Chemical Engineering · 2022
Typearticle
Languageen
FieldPhysics and Astronomy
TopicModel Reduction and Neural Networks
Canadian institutionsnot available
Fundersnot available
KeywordsOrdinary differential equationComputer sciencePhenomenology (philosophy)Differential equationArtificial neural networkPartial differential equationApplied mathematicsMathematicsArtificial intelligenceMathematical analysis

Abstract

fetched live from OpenAlex

Abstract Universal differential equations are a concept in scientific machine learning that leverages the potential of the universal approximator theorem and the physical knowledge of a given system. Creating this level of hybridization within a stiff partial differential equation system is a challenge. On the other hand, adsorption phenomenological models have sink/source terms that describe the adsorption equilibrium through a well‐known simplified model (e.g., Langmuir; Sips; and Brunauer, Emmet, Teller [BET]). These suitable mechanistic assumptions are identified through experiments, providing the parameters of the sink/source model. However, these mechanistic assumptions are a simplification of the system phenomenology. Therefore, the resulting model is limited by its premises. In this scenario, the universal ordinary differential equations (UODE) is presented as an approach that conciliates the potential of artificial neural networks to learn given phenomena without conceptual simplifications. On the other hand, keeping into consideration the system physics. This work proposes a UODE system to solve the multicomponent separation by adsorption in a fixed bed column. Experimental data is used to identify the hybrid model. The required amount of data used in the model identification demonstrates that hybrid models can use a few data points to precisely describe the system. Furthermore, the obtained model can describe competitive adsorption with higher precision than the Langmuir model.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Simulation or modeling · Consensus signal: Simulation or modeling
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.204
Threshold uncertainty score0.216

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.034
GPT teacher head0.239
Teacher spread0.206 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it