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Record W4292212707 · doi:10.1139/cjc-2022-0105

Impact of calcination temperature on the spin–spin relaxation time (<i>T</i><sub>2</sub>) of MgFe<sub>2</sub>O<sub>4</sub> nanoparticles (in vitro)

2022· article· en· W4292212707 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

venuePublished in a venue whose home country is Canada.
no affNo Canadian affiliation: this work is invisible to an affiliation-only frame.
No Canadian affiliation. An affiliation-only frame, the usual design, would never have seen this work. It is one of the works that make the case for inverting the frame.

Bibliographic record

VenueCanadian Journal of Chemistry · 2022
Typearticle
Languageen
FieldMaterials Science
TopicMagnetic Properties and Synthesis of Ferrites
Canadian institutionsnot available
Fundersnot available
KeywordsCalcinationElectron paramagnetic resonanceChemistryFourier transform infrared spectroscopyAnalytical Chemistry (journal)SuperparamagnetismNuclear chemistryNuclear magnetic resonanceMagnetizationChemical engineeringOrganic chemistryMagnetic field

Abstract

fetched live from OpenAlex

MgFe 2 O 4 nanoparticles were prepared by the sol–gel method at calcination temperatures of 300 and 500 °C. Then, the effect of calcination temperature on their structural, magnetic, and cytotoxic properties was investigated. In this regard, X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), and Fourier transform infrared spectroscopy (FTIR) techniques were used to study structural features, vibrating sample magnetometry (VSM) and electron paramagnetic resonance spectroscopy (EPR) methods were used to evaluate the magnetic properties, and the 3-(4,5-dimethylthiazol-2-yl)-2,5-diphenyltetrazolium bromide (MTT) test was used to evaluate the cytotoxicity. XRD and FESEM results showed that the particle size should increase with increasing calcination temperature. FTIR spectra indicated the presence of absorption bands in the range 390–560 cm −1 at both calcination temperatures, which is a common feature of spinel ferrite. Also, the VSM analysis showed that the superparamagnetic property decreases with increasing calcination temperature. Spin–spin relaxation time ( T 2 ) was evaluated as one of the important parameters in increasing the quality of magnetic resonance imaging scans by EPR. EPR results showed that the T 2 increases with increasing calcination temperature. The cytotoxic effects (MTT test) of MgFe 2 O 4 nanoparticles at different concentrations on normal human fibroblast cells (HU-02) showed dose-dependent cell death. This study showed that lowering the calcination temperature can improve the spin–spin contrast ( T 2 ).

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.001
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.005
Threshold uncertainty score0.900

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.001
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0010.000
Research integrity0.0000.001
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.008
GPT teacher head0.203
Teacher spread0.195 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it