Impact of Hierarchical Cation-Exchange Membranes’ Chemistry and Crosslinking Level on Electrodialysis Demineralization Performances of a Complex Food Solution
Why this work is in the frame
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Bibliographic record
Abstract
Hierarchical cation-exchange membranes (hCEMs) fabricated by blade coating and UV crosslinking of ionomer on top of a porous substrate demonstrated promising results in performing NaCl demineralization. In the food industry, complex solutions are used and hCEMs were never investigated before for these food applications. The performances of two different coating chemistries (urethane acrylate based: UL, and acrylic acid based: EbS) and three crosslinking degrees (UL5, UL6, UL7 for UL formulations, and EbS-1, EbS-2, EbS-3 for EbS formulations) were formulated. The impacts of hCEMs properties and crosslinking density on whey demineralization performances by electrodialysis (ED) were evaluated and compared to CMX, a high performing CEM for whey demineralization by ED. The crosslinking density had an impact on the hCEMs area specific resistance, and on the ionic conductance for EbS membrane. However, 70% demineralization of 18% whey solution was reached for the first time for hCEMs without any fouling observed, and with comparable performances to the CMX benchmark. Although some properties were impacted by the crosslinking density, the global performances in ED (limiting current, demineralization duration, global system resistance, energy consumption, current efficiency) for EbS and UL6 membranes were similar to the CMX benchmark. These promising results suggest the possible application of these hCEMs (UL6, EbS-2, and EbS-3) for whey demineralization by ED and more generally complex products as an alternative in the food industry.
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Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.001 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it