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Record W4321365689 · doi:10.1080/21622515.2023.2177200

Remediation of organic contaminated soil by Fe-based nanoparticles and surfactants: a review

2023· review· en· W4321365689 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.
fundA Canadian funder is recorded on the work.

Bibliographic record

VenueEnvironmental Technology Reviews · 2023
Typereview
Languageen
FieldEngineering
TopicEnvironmental remediation with nanomaterials
Canadian institutionsConcordia University
FundersNatural Sciences and Engineering Research Council of CanadaConcordia University
KeywordsEnvironmental remediationPulmonary surfactantNanoparticleZerovalent ironAdsorptionSoil contaminationEnvironmental chemistryContaminationChemistryReductive dechlorinationOrganic matterMaterials scienceBiodegradationNanotechnologyOrganic chemistry

Abstract

fetched live from OpenAlex

Surfactants and nanoparticles have been effectively used for environmental remediation for many years. Over the years, various methods have been developed to synthesize nanoparticles using different surfactants to obtain a s higher treatment efficiency for organic contaminated soil. Compared to conventional remediation methods, the in-situ remediation technique provides advantages, such as being more eco-friendly and cost-effective. This review provides an overview of the remediation of organic contaminated soil using surfactant-stabilized Fe-based nanoparticles, mostly surfactant-stabilized nanoscale zero-valent iron (nZVI). In addition, the use of other stabilizers and the mechanisms of stabilization are discussed. The combination of surfactants and Fe-based nanoparticles can be effectively used to remediate organic contaminants from soil, such as trichloroethylene (up to 99%), polychlorinated biphenyls (up to 80%), perchloroethylene (up to 93%). The treatment efficiency organic contaminants in soil by surfactant-stabilized nanoparticles is higher than only surfactant (less than 90%) or nanoparticles (less than 80%) due to the synergistic effects between surfactants and nanoparticles. This technique is generally more effective to use as a strong reductant, such as reductive dehalogenation or reductive immobilization of metals, while less cost-effective as an adsorbent. In addition, the remediation rate depends on various factors, such as pH, temperature, natural organic matter, ionic strength, type and concentration of stabilizers, site characteristics, contaminant features, nanoparticle and surfactant properties. However, short lifetimes or potential toxicity of nanoparticles are some limitations of this technique.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow), Insufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Not applicable · Consensus signal: none
GenreCandidate signal: Review · Consensus signal: Review
Teacher disagreement score0.945
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0010.001
Meta-epidemiology (broad)0.0030.000
Bibliometrics0.0000.001
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0010.000
Insufficient payload (model declined to judge)0.0000.001

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.019
GPT teacher head0.247
Teacher spread0.228 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it