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Record W4367835313 · doi:10.1021/acs.chemrev.2c00816

Thermal Stability of Cellulose Nanomaterials

2023· review· en· W4367835313 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.
fundA Canadian funder is recorded on the work.

Bibliographic record

VenueChemical Reviews · 2023
Typereview
Languageen
FieldMaterials Science
TopicAdvanced Cellulose Research Studies
Canadian institutionsUniversity of British Columbia
FundersNatural Sciences and Engineering Research Council of CanadaFPInnovationsCanada Foundation for Innovation
KeywordsThermal stabilityChemistryNanomaterialsCelluloseCellulosic ethanolThermalNanotechnologyOrganic chemistryThermodynamicsMaterials science

Abstract

fetched live from OpenAlex

Thermal stability is a crucial property of materials, especially when they have a wide range of thermally sensitive applications. Cellulose nanomaterials (CNMs) extracted from cellulosic biomass have garnered significant attention due to their abundance, biodegradability, sustainability, production scalability, and industrial versatility. To explore the correlation between the structure, chemistry, and morphology of CNMs and their thermal stability, we present a comprehensive literature review. We identify five major factors affecting CNMs' thermal stability, namely type, source, reaction conditions, post-treatment, and drying method, and analyze their impact on CNMs' thermal stability using several case studies from the literature. Using multiple linear least-squares regression (MLR), we establish a quantitative relationship between thermal stability and seven variables: crystallinity index of the source, dissociation constant of the reactant used, reactant concentration, reaction temperature, reaction time, evaporation rate, and post-treatment presence. By understanding these interdependencies, our statistical analysis enables the design of CNMs with predictable thermal properties and identification of optimal conditions for achieving high thermal stability. The results of our study provide crucial insights that can guide the development of CNMs with enhanced thermal stability for use in a variety of industrial applications.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.003
metaresearch head score (Gemma)0.004
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow), Insufficient payload (model declined to judge)
Consensus categoriesInsufficient payload (model declined to judge)
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Not applicable · Consensus signal: none
GenreCandidate signal: Review · Consensus signal: Review
Teacher disagreement score0.824
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0030.004
Meta-epidemiology (narrow)0.0010.000
Meta-epidemiology (broad)0.0050.001
Bibliometrics0.0000.001
Science and technology studies0.0000.001
Scholarly communication0.0000.000
Open science0.0010.001
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0020.004

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.195
GPT teacher head0.413
Teacher spread0.217 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it