MétaCan
← all works

Revealing the closed pore formation of waste wood-derived hard carbon for advanced sodium-ion battery

2023· article· en· 764 citations· W4387098915 on OpenAlex· 10.1038/s41467-023-39637-5

Why is this work in the frame?

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

Canadian funderA Canadian agency funded it. The work may carry no Canadian affiliation at all.

No Canadian affiliation. An affiliation-only frame — the usual design — would never have seen this work. It is one of the works that make the case for inverting the frame.

Abstract

Abstract Although the closed pore structure plays a key role in contributing low-voltage plateau capacity of hard carbon anode for sodium-ion batteries, the formation mechanism of closed pores is still under debate. Here, we employ waste wood-derived hard carbon as a template to systematically establish the formation mechanisms of closed pores and their effect on sodium storage performance. We find that the high crystallinity cellulose in nature wood decomposes to long-range carbon layers as the wall of closed pore, and the amorphous component can hinder the graphitization of carbon layer and induce the crispation of long-range carbon layers. The optimized sample demonstrates a high reversible capacity of 430 mAh g −1 at 20 mA g −1 (plateau capacity of 293 mAh g −1 for the second cycle), as well as good rate and stable cycling performances (85.4% after 400 cycles at 500 mA g −1 ). Deep insights into the closed pore formation will greatly forward the rational design of hard carbon anode with high capacity.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

The record

Venue
Nature Communications
Topic
Advancements in Battery Materials
Field
Engineering
Canadian institutions
Funders
Argonne National LaboratoryScience and Technology Program of Hunan ProvinceInnovation and Technology FundCentral South UniversityNational Natural Science Foundation of ChinaCanada Excellence Research Chairs, Government of CanadaU.S. Department of Energy
Keywords
Carbon fibersBattery (electricity)SodiumIonSodium-ion batteryMaterials scienceChemical engineeringNanotechnologyChemistryComposite materialOrganic chemistryAnodeComposite numberMetallurgyPhysicsEngineeringPhysical chemistryElectrode
Has abstract in OpenAlex
yes