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Record W4388105058 · doi:10.1029/2023je008041

Mineralogical Investigation of Mg‐Sulfate at the Canaima Drill Site, Gale Crater, Mars

2023· article· en· W4388105058 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.
fundA Canadian funder is recorded on the work.

Bibliographic record

VenueJournal of Geophysical Research Planets · 2023
Typearticle
Languageen
FieldPhysics and Astronomy
TopicPlanetary Science and Exploration
Canadian institutionsAlberta EnergyUniversity of CalgaryUniversity of New BrunswickUniversity of Guelph
FundersCanadian Space Agency
KeywordsMars Exploration ProgramAmorphous solidImpact craterSulfateRelative humidityMartian surfaceMineralogyGeologyMartianAnalytical Chemistry (journal)AstrobiologyChemistryMaterials scienceCrystallographyMetallurgyEnvironmental chemistryMeteorology

Abstract

fetched live from OpenAlex

Abstract For the first time on Mars, the crystalline magnesium‐sulfate mineral starkeyite (MgSO 4 ‧4H 2 O) was definitively identified using the CheMin X‐ray diffraction instrument at Gale crater. At the Canaima drill site, starkeyite along with amorphous MgSO 4 ‧ n H 2 O are among the “polyhydrated Mg‐sulfates” interpreted in orbital reflectance spectra. Mg‐sulfates are good climate indicators as they are very responsive to changes in temperature and relative humidity. We hypothesize that, through evaporation, Mg‐sulfates formed at the end of brine evolution when ion concentrations became saturated and precipitated on the surface or near sub‐surface as either epsomite or meridianiite. These minerals were subsequently dehydrated later to starkeyite and amorphous MgSO 4 ‧ n H 2 O in response to a drier Mars. At Canaima, starkeyite is stable and would form during the warmer Mars summers. Due to very slow kinetics at the low Mars winter temperatures, starkeyite and amorphous MgSO 4 ‧ n H 2 O would be resistant to recrystallize to more hydrous forms and thus likely persist year‐round. During the course of analyses, starkeyite transforms into amorphous MgSO 4 ‧ n H 2 O inside the rover body due to the elevated temperature and greatly reduced relative humidity compared to the martian surface at the Canaima drill site. It is possible that crystalline sulfate minerals existed in earlier samples measured by CheMin but altered inside the rover before they could be analyzed. Starkeyite is most likely prevalent in the subsurface, whereas both starkeyite and amorphous MgSO 4 ‧ n H 2 O are likely present on the surface as starkeyite could partially transform into amorphous MgSO 4 ‧ n H 2 O due to direct solar heating.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Observational · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.735
Threshold uncertainty score0.773

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.001
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.001

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.073
GPT teacher head0.322
Teacher spread0.249 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it