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Record W4388498464 · doi:10.1021/acssuschemeng.3c04108

Chemical Binder-Free and Oven-Dried Lignocellulose/Clay Composite Foams: Flame Resistance, Thermal Insulation, and Recyclability

2023· article· en· W4388498464 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.
fundA Canadian funder is recorded on the work.

Bibliographic record

VenueACS Sustainable Chemistry & Engineering · 2023
Typearticle
Languageen
FieldMaterials Science
TopicFlame retardant materials and properties
Canadian institutionsUniversity of British Columbia
FundersMinistry of Forests, Lands and Natural Resource OperationsCanada Research ChairsCanada Excellence Research Chairs, Government of CanadaCanada Foundation for Innovation
KeywordsMaterials scienceComposite materialFire retardantComposite numberCompressive strengthLimiting oxygen indexPyrolysisChemical resistanceCharWaste management

Abstract

fetched live from OpenAlex

Global efforts to reduce carbon emissions and improve thermal comfort demand sustainable and safe-to-use insulative materials. This study advances a new type of chemical binder-free lignocellulose/clay composite foam as a sustainable alternative to the currently used synthetic and glass/mineral counterparts. Pressurized disk milling unraveled submicron “hairy” fibrillation on the surface of refiner mechanical pulp (RMP). Such fibrillated fibers were then subjected to a foam laying process, with kaolinite being incorporated as an efficient and cost-effective fire retardant. Upon oven drying, the foams display suitable structural and mechanical robustness. Through mild fibrillation treatment of the RMP, a clay retention of up to 2-fold by weight was achieved without compromising the properties of the foam, removing the need for the addition of chemical binders. The foam density, mechanical and thermal properties, and flame resistance were systematically investigated with respect to the relative fiber loading as well as surfactant and clay addition. A low thermal conductivity (43.7 ± 0.7 mW/(m·K)) and high flame resistance (limiting oxygen index of ∼43%) were demonstrated for hybrid foams of apparent density of 136 ± 1 kg/m 3 that also displayed good compressive strength (Young’s modulus of 0.805 ± 0.158 MPa and compressive stress of 0.126 ± 0.008 MPa at 25% strain). Remarkably, owing to the absence of chemical binding, facile recyclability was demonstrated over three cycles, with no significant reduction in performance. Overall, this work proposes a readily scalable technology toward safe-to-use, recyclable lignocellulose/clay composite foams for building insulation.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.004
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.006
GPT teacher head0.182
Teacher spread0.176 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it