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Record W4391317325 · doi:10.1002/adfm.202312550

Unveiling the Pivotal Parameters for Advancing High Energy Density in Lithium‐Sulfur Batteries: A Comprehensive Review

2024· review· en· W4391317325 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.
fundA Canadian funder is recorded on the work.

Bibliographic record

VenueAdvanced Functional Materials · 2024
Typereview
Languageen
FieldEngineering
TopicAdvanced Battery Materials and Technologies
Canadian institutionsUniversity of Alberta
FundersNatural Sciences and Engineering Research Council of CanadaAlberta InnovatesCanada First Research Excellence FundUniversity of Alberta
KeywordsMaterials scienceEnergy densityLithium (medication)SulfurLithium–sulfur batteryEnergy storageEngineering physicsEnergy (signal processing)NanotechnologyThermodynamicsBattery (electricity)MetallurgyEngineeringPhysicsPower (physics)

Abstract

fetched live from OpenAlex

Abstract The lithium‐sulfur (Li‐S) battery stands as a strong contender for the next‐generation energy storage system, characterized by abundant sulfur resources, environmental sustainability, and high specific capacity. However, its energy density remains constrained by factors such as low sulfur loading and fraction in the cathode, excessive electrolyte, and an excess of anode. These mild conditions significantly limit the energy density of Li‐S batteries, making them less competitive. To achieve higher energy density, harsh operation conditions are necessary, but these remain challenging to implement, even in a lab‐scale production. In this comprehensive review, the emphasis will be on recent advancements in Li‐S batteries, specifically in the realm of designing high sulfur loading, high sulfur fraction, lean electrolyte, and low limited negative electrode Li‐S batteries. A visualizable model that illustrates the relationship between cell energy density and various cell parameters, underscoring the importance of exploring Li‐S batteries under extreme operating conditions for further development is provided. Furthermore, it will discussed the possibilities of achieving even higher energy density in Li‐S batteries and the challenges that need to be addressed to make them practical for real‐world applications.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Not applicable · Consensus signal: none
GenreCandidate signal: Review · Consensus signal: Review
Teacher disagreement score0.930
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0010.001
Meta-epidemiology (broad)0.0030.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.030
GPT teacher head0.272
Teacher spread0.242 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it