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Navigating Materials Space with ML-Generated Electronic Fingerprints

2024· preprint· en· W4399560162 on OpenAlexafffund
Ihor Neporozhnii, Zhibo Wang, Rochan Bajpai, Camilo Ariel Jaime Gomez, Nirvik Chakraborty, Tony Dong, Isaac Tamblyn, Oleksandr Voznyy

Bibliographic record

VenueChemRxiv · 2024
Typepreprint
Languageen
FieldMaterials Science
TopicMachine Learning in Materials Science
Canadian institutionsUniversity of OttawaUniversity of Toronto
FundersNatural Sciences and Engineering Research Council of Canada
KeywordsElectronic structureComputer scienceSimilarity (geometry)Fingerprint (computing)Property (philosophy)PhotovoltaicsData miningMaterials scienceArtificial intelligenceComputational chemistryChemistry

Abstract

fetched live from OpenAlex

Finding materials with good performance in a specific application, especially when the origin of good performance is not well understood or not easily computable, is a major challenge in materials science. Trial-and-error random exploration is prohibitively expensive due to the vastness of the materials space. A more practical approach is to search for new materials within the proximity of known compounds that possess the desired property. In such an approach, assessing materials’ similarity requires deriving some fingerprint relevant for material’s performance. Typically, material’s structure is used as the fingerprint, which often does not translate into similarity in properties. Electronic structure fingerprints, e.g., density of states (DOS) or electronic band structure, were proposed as a better alternative, however, the computational cost of their calculation on the scale of 100,000 materials remains too high for rapid exploration. In this work, we developed a Graph Convolutional Network (GCN) ProDosNet which is trained on orbital-resolved and atom-resolved projected density of states (PDOS) data and is capable of predicting the electronic structure of materials at extremely low computational cost. With this model, we were able to generate PDOS fingerprints for all compounds present in the Materials Projects database and cluster them by similarity of their orbital-resolved PDOS. We demonstrate that these electronic fingerprints allow finding materials with similar electronic properties but drastically different structures for applications in photovoltaics, catalysis, and batteries.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.002
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Simulation or modeling · Consensus signal: Simulation or modeling
GenreCandidate signal: Empirical · Consensus signal: none
Teacher disagreement score0.005
Threshold uncertainty score0.011

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0010.002
Meta-epidemiology (narrow)0.0010.000
Meta-epidemiology (broad)0.0010.001
Bibliometrics0.0010.001
Science and technology studies0.0000.001
Scholarly communication0.0010.001
Open science0.0020.001
Research integrity0.0010.001
Insufficient payload (model declined to judge)0.0030.001

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.011
GPT teacher head0.280
Teacher spread0.269 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designSimulation or modeling
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations3
Published2024
Admission routes2
Has abstractyes

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