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Navigating Materials Space with ML-Generated Electronic Fingerprints

2024· preprint· en· W4399560162 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.
fundA Canadian funder is recorded on the work.

Bibliographic record

VenueChemRxiv · 2024
Typepreprint
Languageen
FieldMaterials Science
TopicMachine Learning in Materials Science
Canadian institutionsUniversity of OttawaUniversity of Toronto
FundersNatural Sciences and Engineering Research Council of Canada
KeywordsElectronic structureComputer scienceSimilarity (geometry)Fingerprint (computing)Property (philosophy)PhotovoltaicsData miningMaterials scienceArtificial intelligenceComputational chemistryChemistry

Abstract

fetched live from OpenAlex

Finding materials with good performance in a specific application, especially when the origin of good performance is not well understood or not easily computable, is a major challenge in materials science. Trial-and-error random exploration is prohibitively expensive due to the vastness of the materials space. A more practical approach is to search for new materials within the proximity of known compounds that possess the desired property. In such an approach, assessing materials’ similarity requires deriving some fingerprint relevant for material’s performance. Typically, material’s structure is used as the fingerprint, which often does not translate into similarity in properties. Electronic structure fingerprints, e.g., density of states (DOS) or electronic band structure, were proposed as a better alternative, however, the computational cost of their calculation on the scale of 100,000 materials remains too high for rapid exploration. In this work, we developed a Graph Convolutional Network (GCN) ProDosNet which is trained on orbital-resolved and atom-resolved projected density of states (PDOS) data and is capable of predicting the electronic structure of materials at extremely low computational cost. With this model, we were able to generate PDOS fingerprints for all compounds present in the Materials Projects database and cluster them by similarity of their orbital-resolved PDOS. We demonstrate that these electronic fingerprints allow finding materials with similar electronic properties but drastically different structures for applications in photovoltaics, catalysis, and batteries.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.002
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow), Scholarly communication, Insufficient payload (model declined to judge)
Consensus categoriesInsufficient payload (model declined to judge)
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.009
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0020.000
Meta-epidemiology (narrow)0.0010.001
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0020.000
Open science0.0010.003
Research integrity0.0000.002
Insufficient payload (model declined to judge)0.0040.003

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.011
GPT teacher head0.280
Teacher spread0.269 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it