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Record W4404297422 · doi:10.1007/s43832-024-00163-0

Screening of municipal effluents with the peroxidase toxicity assay

2024· article· en· W4404297422 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.

Bibliographic record

VenueDiscover Water · 2024
Typearticle
Languageen
FieldChemistry
TopicDye analysis and toxicity
Canadian institutionsEnvironment and Climate Change Canada
Fundersnot available
KeywordsEffluentToxicityPeroxidaseEnvironmental chemistryEnvironmental scienceChemistryToxicologyPulp and paper industryMedicineBiologyInternal medicineEnvironmental engineeringEngineeringBiochemistryEnzyme

Abstract

fetched live from OpenAlex

Abstract The peroxidase (Per) reaction is a quick and inexpensive biosensor for the screening of environmental contaminants and wastewaters. The purpose of this study was to screen various municipal wastewaters before and after 7 different types of treatment processes using this sensor to identify potential sites under stress by urban pollution. The following wastewater samples before (influent) and after the commonly applied treatments (effluent) were tested using the Per activity test: advanced biofiltration, biofiltration, aerated lagoons, secondary aeration sludge, trickling filter, secondary membrane filtration, and primary. The influents and effluents were collected for 3 days and concentrated to 500 X on a reverse-phase (C18) extraction cartridge. The ethanol extracts were examined for dissolved organic carbon, plastic-like materials, polyaromatic hydrocarbons and polystyrene nanoplastics. The samples were then tested using the Per reaction alone and in the presence of DNA to detect DNA binding agents. The results show that population size tended to increase Per activity and 60% of the effluents decreased Per activity leading to H 2 O 2 persistence and toxicity. More advanced treatments (biofiltration, membrane biofiltration, secondary aeration) produced stronger changes from the corresponding untreated influents corroborating their performance in reducing toxicity. The addition of DNA during the Per reaction revealed that population size had no influence and that 60% of treated effluents restored Per activity suggesting release of genotoxic compounds in the aquatic environment from treated wastewaters. The toxic implications of the continuous release of wastewaters in aquatic ecosystems are discussed in the light of emerging contaminants such as nanoplastics.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesInsufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.033
Threshold uncertainty score0.999

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0020.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.011
GPT teacher head0.238
Teacher spread0.227 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it