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Record W4409284864 · doi:10.1021/acs.iecr.5c00324

Technoeconomic Analysis of the Supercritical Fluid Extraction Process for the Extraction of Rare Earth Elements from Ores

2025· article· en· W4409284864 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.
fundA Canadian funder is recorded on the work.
aboutThe title or abstract carries a Canadian signal from the geographic lexicon.

Bibliographic record

VenueIndustrial & Engineering Chemistry Research · 2025
Typearticle
Languageen
FieldEngineering
TopicExtraction and Separation Processes
Canadian institutionsNatural Resources CanadaUniversity of Toronto
FundersNatural Resources Canada
KeywordsRare earthExtraction (chemistry)Supercritical fluidSupercritical fluid extractionProcess (computing)ChemistrySolvent extractionProcess engineeringChromatographyMineralogyComputer scienceEngineeringOrganic chemistry

Abstract

fetched live from OpenAlex

This study investigates the technoeconomic feasibility of utilizing supercritical fluid extraction (SCFE) with supercritical CO 2 and a tributyl phosphate–nitric acid (TBP-HNO 3 ) adduct for recovering rare earth elements (REEs) from the complex zircon-rich mineral concentrate. A detailed technoeconomic analysis (TEA) framework is employed, integrating mass and energy balance calculations, economic modeling, scenario evaluation, and sensitivity analysis. The research aims to establish the economic viability and scalability of SCFE technology as a sustainable alternative to conventional extraction methods. The study focused on an industrial-scale facility in Ontario, Canada, equipped with a 4000 L SCFE reactors. Key findings included first-year operational expenditures approaching 3 million USD and total capital expenditures of 13.7 million to 14.6 million USD. Revenue from the extracted REEs varied, with the highest returns associated with high-value elements such as terbium and dysprosium. Sensitivity analysis highlights that the profitability of the process is most sensitive to REE prices, particularly for Nd 2 O 3, Dy 2 O 3, and Tb 4 O 7, followed by reagent costs and utility expenses. Payback periods ranged from 6.9 years in the optimal scenario to 12.8 years in less favorable configurations. This study demonstrates the potential of SCFE as a viable technology for REE recovery, emphasizing the importance of feedstock optimization, cost-effective reagent usage, and scalability.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.001
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.028
Threshold uncertainty score0.381

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.001
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.001
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.001
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.071
GPT teacher head0.384
Teacher spread0.313 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it