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Record W4409284864 · doi:10.1021/acs.iecr.5c00324

Technoeconomic Analysis of the Supercritical Fluid Extraction Process for the Extraction of Rare Earth Elements from Ores

2025· article· en· W4409284864 on OpenAlexafffundabout
Gisele Azimi, Maziar E. Sauber, Sicheng Li

Bibliographic record

VenueIndustrial & Engineering Chemistry Research · 2025
Typearticle
Languageen
FieldEngineering
TopicExtraction and Separation Processes
Canadian institutionsNatural Resources CanadaUniversity of Toronto
FundersNatural Resources Canada
KeywordsRare earthExtraction (chemistry)Supercritical fluidSupercritical fluid extractionProcess (computing)ChemistrySolvent extractionProcess engineeringChromatographyMineralogyComputer scienceEngineeringOrganic chemistry

Abstract

fetched live from OpenAlex

This study investigates the technoeconomic feasibility of utilizing supercritical fluid extraction (SCFE) with supercritical CO 2 and a tributyl phosphate–nitric acid (TBP-HNO 3 ) adduct for recovering rare earth elements (REEs) from the complex zircon-rich mineral concentrate. A detailed technoeconomic analysis (TEA) framework is employed, integrating mass and energy balance calculations, economic modeling, scenario evaluation, and sensitivity analysis. The research aims to establish the economic viability and scalability of SCFE technology as a sustainable alternative to conventional extraction methods. The study focused on an industrial-scale facility in Ontario, Canada, equipped with a 4000 L SCFE reactors. Key findings included first-year operational expenditures approaching 3 million USD and total capital expenditures of 13.7 million to 14.6 million USD. Revenue from the extracted REEs varied, with the highest returns associated with high-value elements such as terbium and dysprosium. Sensitivity analysis highlights that the profitability of the process is most sensitive to REE prices, particularly for Nd 2 O 3, Dy 2 O 3, and Tb 4 O 7, followed by reagent costs and utility expenses. Payback periods ranged from 6.9 years in the optimal scenario to 12.8 years in less favorable configurations. This study demonstrates the potential of SCFE as a viable technology for REE recovery, emphasizing the importance of feedstock optimization, cost-effective reagent usage, and scalability.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.001
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Simulation or modeling · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.019
Threshold uncertainty score0.039

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0010.001
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.001
Bibliometrics0.0010.001
Science and technology studies0.0000.000
Scholarly communication0.0010.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.071
GPT teacher head0.384
Teacher spread0.313 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designSimulation or modeling
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations7
Published2025
Admission routes3
Has abstractyes

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