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Record W4410291492 · doi:10.1016/j.mtener.2025.101913

Evaluation of niobium-based bipolar plates with ultra-low precious metal coatings for high-performance and durable PEM water electrolyzers

2025· article· en· W4410291492 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.
fundA Canadian funder is recorded on the work.

Bibliographic record

VenueMaterials Today Energy · 2025
Typearticle
Languageen
FieldEnergy
TopicHybrid Renewable Energy Systems
Canadian institutionsUniversity of WaterlooUniversité du Québec à Trois-Rivières
FundersNatural Sciences and Engineering Research Council of CanadaMitacsCanada Research Chairs
KeywordsMaterials scienceNiobiumProton exchange membrane fuel cellComposite materialPrecious metalMetalMetallurgyChemical engineeringFuel cells

Abstract

fetched live from OpenAlex

The performance of bipolar plates (BPPs) significantly impacts the durability and efficiency of proton exchange membrane water electrolyzers (PEMWEs). This study explores the potential of niobium (Nb) as a BPP substrate, assessing its performance against commercial pure titanium (CP-Ti) and 316L-stainless steel (SS316L). To further improve Nb's performance, 120 nm thin layer of platinum coating (Nb-Pt120) is applied using magnetron sputtering. Electrochemical tests are performed alongside interfacial contact resistance (ICR), wettability and surface characterization. Nb demonstrates superior corrosion resistance, hydrophobicity, lower ICR, and enhanced durability, establishing it as a promising candidate for BPPs. With Pt coating, the results reveal that Nb-Pt120 exhibits a significantly lower corrosion current density ( i corr ) of approximately 0.8 μA.cm −2 meeting the DOE technical targets. Additionally, Nb-Pt120 demonstrates reduced ICR (<10.0 mΩ.cm 2 ), greater hydrophobicity, and enhanced electrochemical stability compared to both uncoated and other Pt-coated substrates. The Nb-Pt120 BPP maintains durability for over 41 hours (approximately 20 and 40 times longer than Ti-Pt120 and SS316L-Pt120, respectively) under accelerated stress test at a constant current density of +2.0 A.cm −2 . This study establishes Nb as a superior substrate for BPPs in PEMWEs, with additional performance benefits realized through Pt coating, providing a path toward more durable water electrolyzer systems.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.002
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.119
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0020.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.007
GPT teacher head0.208
Teacher spread0.202 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it