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Optimizing non-dispersive infrared channels for derived cetane number prediction: Impact of spectral resolution and feature selection

2025· article· en· W4412978674 on OpenAlexfundno aff
Ashish Sutar, Eric Mayhew, Kenneth Brezinsky, Patrick T. Lynch

Bibliographic record

VenueChemometrics and Intelligent Laboratory Systems · 2025
Typearticle
Languageen
FieldEngineering
TopicAdvanced Chemical Sensor Technologies
Canadian institutionsnot available
FundersDEVCOM Army Research LaboratoryArmy Research LaboratoryCanadian Orthopaedic Trauma Society
KeywordsCetane numberFeature selectionSelection (genetic algorithm)Feature (linguistics)Resolution (logic)ChemometricsInfraredPattern recognition (psychology)Computer scienceArtificial intelligenceChemistryPhysicsOpticsMachine learning

Abstract

fetched live from OpenAlex

Jet fuels exhibit considerable variability in their chemical properties. This variability impacts properties like Derived Cetane Number (DCN), a measure of ignition quality that can vary significantly in the commercial fuel supply as it is not specified for jet fuels. Conventional methods for measuring DCN, such as Ignition Quality Testers, are accurate but rely on large equipment and long measurement times making them impractical for portable use. Vibrational spectroscopy offers a promising alternative, linking spectral information to fuel properties, yet high-resolution spectrometers remain bulky and challenging to miniaturize. Non-dispersive infrared (NDIR) sensors provide a compact solution, capable of accessing a few key spectral elements to predict fuel properties. Despite their lower number of elements and typically lower resolution, NDIR sensors are low-cost, power-efficient, and compact, making them ideal for onboard or handheld applications. This study extends analysis previously performed in the near-infrared region (4000-12000 cm -1 ) to the mid-infrared region (714-1428 cm -1 ), evaluating both commercial off-the-shelf (COTS) and custom narrow-bandwidth channels. Using a channel optimization process, custom channels with a 2 cm -1 bandwidth and 50% overlap achieved an R 2 of 0.92 in a linear model, closely matching the performance of high-resolution methods. Additionally, a nonlinear support vector regression (SVR) model further improved predictions, achieving an R 2 of 0.93 with just ten channels. These findings suggest that well-designed NDIR sensors can deliver accurate DCN predictions, offering a practical alternative to larger spectrometers. This approach holds promise for real-time fuel analysis in portable applications, bridging the gap between accuracy and miniaturization.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.002
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.004
Threshold uncertainty score0.009

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0010.002
Meta-epidemiology (narrow)0.0010.000
Meta-epidemiology (broad)0.0010.001
Bibliometrics0.0010.001
Science and technology studies0.0000.000
Scholarly communication0.0010.001
Open science0.0010.000
Research integrity0.0010.001
Insufficient payload (model declined to judge)0.0010.001

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.009
GPT teacher head0.246
Teacher spread0.237 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations1
Published2025
Admission routes1
Has abstractyes

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