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Record W4414169066 · doi:10.1002/anie.202512409

Biomedical Applications of Nanozymes: An Enzymology Perspective

2025· article· en· W4414169066 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

fundA Canadian funder is recorded on the work.
no affNo Canadian affiliation: this work is invisible to an affiliation-only frame.
No Canadian affiliation. An affiliation-only frame, the usual design, would never have seen this work. It is one of the works that make the case for inverting the frame.

Bibliographic record

VenueAngewandte Chemie International Edition · 2025
Typearticle
Languageen
FieldMaterials Science
TopicAdvanced Nanomaterials in Catalysis
Canadian institutionsnot available
FundersChina Scholarship CouncilNatural Sciences and Engineering Research Council of CanadaInnovation and Technology Commission - Hong KongCanada Research Chairs
KeywordsContext (archaeology)Perspective (graphical)Mechanism (biology)Catalysis

Abstract

fetched live from OpenAlex

Nanozymes are catalytic nanomaterials that transform enzyme substrates into their corresponding products, offering enhanced stability and a cost-effective alternative to traditional enzymes. As nanomaterials, they possess unique physicochemical properties and catalytic mechanisms distinct from those of enzymes. Such differences have profound, yet often neglected, implications in biomedical applications. In the context of enzymology, this review compares nanozymes and enzymes, with a focus on redox reactions. This review begins with the classification of nanozymes based on the types of reactions they catalyze, with the ability to exhibit multiple catalytic activities being a prevalent characteristic. The use of the Michaelis-Menten model for both enzymes and nanozymes is discussed in detail, and the Michaelis constant, maximum reaction rate, and turnover number values are compared. The performance of nanozymes in crowded environments and under extreme conditions is also compared to that of enzymes. We discuss the kinetic factors influencing nanozyme performance, the impact of active site shielding, and the activity under non-physiological conditions. We then compiled recent trends in the biomedical applications of nanozymes, focusing on both the production and scavenging of reactive oxygen species. This review links fundamental enzymology to nanozyme catalysis, providing a key reference for the rational use of nanozymes.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesInsufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: none
Teacher disagreement score0.585
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.010
GPT teacher head0.315
Teacher spread0.305 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it