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Record W6990071544

Comparisons between SCIAMACHY atmospheric CO2 retrieved using (FSI) WFM-DOAS to ground based FTIR data and the TM3 chemistry transport model

2006· article· en· W6990071544 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

aboutThe title or abstract carries a Canadian signal from the geographic lexicon.
no affNo Canadian affiliation: this work is invisible to an affiliation-only frame.
No Canadian affiliation. An affiliation-only frame, the usual design, would never have seen this work. It is one of the works that make the case for inverting the frame.

Bibliographic record

VenueMax Planck Institute for Plasma Physics · 2006
Typearticle
Languageen
FieldEnvironmental Science
TopicAtmospheric and Environmental Gas Dynamics
Canadian institutionsnot available
Fundersnot available
KeywordsSCIAMACHYNorthern HemisphereDifferential optical absorption spectroscopyFourier transform infrared spectroscopySpectroscopyNear-infrared spectroscopyAnalytical Chemistry (journal)Absorption (acoustics)Atmosphere (unit)
DOInot available

Abstract

fetched live from OpenAlex

Atmospheric CO2 concentrations, retrieved from spectral measurements made in the near infrared (NIR) by the SCIAMACHY instrument, using Full Spectral Initiation Weighting Function Modified Differential Optical Absorption Spectroscopy (FSI WFM-DOAS), are compared to ground based Fourier Transform Infrared (FTIR) data and to the output from a global chemistry-transport model.
\nAnalysis of the FSI WFM-DOAS retrievals with respect to the ground based FTIR instrument, located at Egbert, Canada, show good agreement with an average negative
\nbias of approximately −4.0% with a standard deviation of ~3.0%. This bias which exhibits an apparent seasonal trend,
\nis of unknown origin, though slight differences between the averaging kernels of the instruments and the limited temporal
\ncoverage of the FTIR data may be the cause. The relative scatter of the retrieved vertical column densities is larger than
\nthe spread of the FTIR measurements. Normalizing the CO2 columns using the surface pressure does not affect the magnitude of this bias although it slightly decreases the scatter of the FSI data.
\nComparisons of the FSI retrievals to the TM3 global chemistry-transport model, performed over four selected Northern Hemisphere scenes show reasonable agreement.
\nThe correlation, between the time series of the SCIAMACHY and model monthly scene averages, are ~0.7 or greater, demonstrating the ability of SCIAMACHY to detect seasonal changes in the CO2 distribution. The amplitude of the seasonal cycle, peak to peak, observed by SCIAMACHY
\nhowever, is larger by a factor of 2–3 with respect to the model, which cannot be explained. The yearly means detected by SCIAMACHY are within 2% of those of the model with the mean difference between the CO2 distributions also approximately 2.0%. Additionally, analysis of the retrieved
\nCO2 distributions reveals structure not evident in the model fields which correlates well with land classification type. 
\nFrom these comparisons, it is estimated that the overall bias of the CO2 columns retrieved by the FSI algorithm is
\n<4.0% with the precision of monthly 1º×1º gridded data close to 1.0%.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Simulation or modeling · Consensus signal: Simulation or modeling
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.147
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0010.001
Scholarly communication0.0000.000
Open science0.0010.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.030
GPT teacher head0.234
Teacher spread0.204 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it