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Effects of post-translational modifications on protein function

2024· article· W7125614161 on OpenAlexfundno aff
Marcus D Everett, Catherine L Fontaine, Robert J Sinclair, Helena M Tremblay

Bibliographic record

VenueInternational Journal of Advanced Biochemistry Research · 2024
Typearticle
Language
FieldMedicine
TopicPeptidase Inhibition and Analysis
Canadian institutionsnot available
FundersNatural Sciences and Engineering Research Council of CanadaCanadian Institutes of Health Research
KeywordsAcetylationCrosstalkPhosphorylationUbiquitinProteomicsGlycosylationPosttranslational modificationSubcellular localizationEnzyme

Abstract

fetched live from OpenAlex

Over 200 distinct types of post-translational modifications have been identified in eukaryotic proteomes, yet the functional consequences of most remain poorly characterized. This research investigated the effects of major post-translational modifications on protein function using an integrated computational and experimental approach. A dataset comprising 847 well-characterized proteins from human cell lines was analyzed for modification patterns and functional outcomes between January 2021 and November 2022 at the Westbrook Institute of Biomedical Research. Mass spectrometry-based proteomics identified modification sites, while functional assays assessed enzymatic activity, protein stability, subcellular localization, and protein-protein interactions. Phosphorylation represented the most prevalent modification at 38.7% of detected sites, followed by ubiquitination at 22.4% and acetylation at 15.3%. Functional impact analysis revealed that phosphorylation predominantly affected enzymatic activity with 82.1% of phosphorylated enzymes showing altered catalytic parameters. Ubiquitination primarily targeted proteins for degradation, reducing stability in 76.8% of modified substrates. Acetylation demonstrated the strongest influence on DNA-binding proteins, with 78.4% of acetylated transcription factors exhibiting modified binding affinity. Glycosylation showed particular importance for protein stability at 81.2% and subcellular localization at 62.4%. Heatmap analysis of modification-function relationships revealed context-dependent effects whereby identical modifications produced opposing outcomes depending on target protein identity and cellular environment. The research identified 127 proteins subject to crosstalk between multiple modification types, suggesting coordinated regulatory networks. These findings establish quantitative relationships between specific modifications and functional outcomes, providing a framework for predicting how alterations in modification machinery contribute to disease pathogenesis and identifying potential therapeutic intervention points.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.002
metaresearch head score (Gemma)0.003
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.003
Threshold uncertainty score0.010

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0020.003
Meta-epidemiology (narrow)0.0010.000
Meta-epidemiology (broad)0.0010.001
Bibliometrics0.0010.002
Science and technology studies0.0000.000
Scholarly communication0.0010.001
Open science0.0000.001
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.025
GPT teacher head0.390
Teacher spread0.364 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2024
Admission routes1
Has abstractyes

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