Screening of Three Light-Oil Reservoirs for Application of Air Injection Process by Accelerating Rate Calorimetric and TG/PDSC Tests
Notice bibliographique
Résumé
Abstract A series of Accelerating Rate Calorimeter (ARC) and Thermo Gravimetric Pressurized Differential Scanning Calorimeter (TG/PDSC) tests was conducted on oil-rock systems from three light-oil reservoirs (Oils A, B and C) to screen and evaluate the potential of the air injection process. ARC tests helped determine, a priori, whether the test oils would autoignite under reservoir conditions of pressure and temperature. Also, the limits of the low temperature range were established and Arrhenius oxidation kinetics parameters were estimated. The goals of the TG/PDSC tests were to identify temperature ranges over which the oil reacted with oxygen in the injected air, and to determine the fraction of the sample responsible for the reactivity. ARC and TG/PDSC tests demonstrate that Oils A and C offer favourable exothermic behaviour in the low temperature range with lower activation energies and low orders of reactions?the conditions typically favouring autoignition. The presence of rock material lowered the ignition temperature, confirming its impact on O2 uptake. Oil A had a lower energy generation (ignition) temperature, and a stronger and smoother transition to the higher temperature region. Both oils responded favourably during isothermal aging with air as manifested by a drop in the initial self-heating temperature (a 15 °C drop for Oil A and a 10 °C drop for Oil C). The third oil, Oil B, showed unusual characteristics, with almost no impact of the core material on the starting temperature of the exotherm; rather, the core material appeared to have acted as a heat sink. Overall, Oil B needed a much higher activation energy to ignite, and its order of reactions was very high. Furthermore, it showed no response to isothermal aging, and hence, it is less likely to autoignite in the reservoir. esults revealed that ARC and TG/PDSC tests could be an effective tool to rank and study the oxidation characteristics in the low temperature range of the candidate oils. Also, it was observed that the oil composition and rock mineralogy are important factors affecting the type and rate of the oxidation reactions occurring in the low temperature range. Introduction The air injection process is now a proven and viable process in improving oil recovery from several light-oil reservoirs. As a result, it has generated much interest in recent years(1–5). Cheap and abundant, air is also touted as a possible alternative to highcost hydrocarbon and CO2 gases in certain circumstances or locations where water is scarce(6–10). Moore et al(11) suggest that in an air injection process in lightoil reservoirs, both oxygen addition and bond scission reactions take place. Oxygen addition reactions are believed to occur at temperatures between 100 °C and 150 °C. These reactions are characterized by heavier oxygenated hydrocarbon products. Bond scission reactions for light oils typically occur at temperatures in the 150 to 300 °C and the 350 to 700 °C range. These reactions produce carbon oxides, water (steam) and heat, which contribute significantly towards mobilizing oil.
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Comment cette classification a été obtenuedéplier
Prédiction distillée sur la base complète
Imitation des enseignantsNi prévalence calibrée, ni vérité terrain. Validation humaine à venir. Apprise à partir de 10 348 étiquettes directes de Codex et de 10 348 étiquettes directes de Gemma. Le mode candidate est l'union des têtes enseignantes seuillées; le consensus est leur intersection. Ces sorties portent le statut machine_predicted_unvalidated et ne sont ni des étiquettes humaines ni des étiquettes directes de modèles de pointe.
Scores Codex et Gemma par catégorie
| Catégorie | Codex | Gemma |
|---|---|---|
| Métarecherche | 0,000 | 0,001 |
| Méta-épidémiologie (sens strict) | 0,000 | 0,000 |
| Méta-épidémiologie (sens large) | 0,000 | 0,000 |
| Bibliométrie | 0,003 | 0,002 |
| Études des sciences et des technologies | 0,000 | 0,000 |
| Communication savante | 0,000 | 0,000 |
| Science ouverte | 0,000 | 0,000 |
| Intégrité de la recherche | 0,000 | 0,000 |
| Charge utile insuffisante (le modèle a refusé de juger) | 0,000 | 0,000 |
Scores machine (provisoires)
Les deux têtes enseignantes du modèle étudiant, lues sur ce travail. Un score ordonne la base pour la relecture; il n'affirme jamais une catégorie, et le statut de validation accompagne chaque rangée tel quel.
Scores de référence d'un modèle non mature (critères de maturité non atteints, 7 itérations). Un score ordonne; il n'affirme jamais une catégorie.
score_only:v0-immature-baseline · tel quel depuis la passe de notation : score_only signifie que le nombre peut ordonner les travaux, et qu'aucune étiquette de catégorie n'en découleClassification
machine, non validéePrédiction automatique; un appel candidat d’une seule tête enseignante, pas un consensus.
Le détail, modèle par modèle et score par score, se trouve en fin de page sous « Comment cette classification a été obtenue ».