A New Emulsified Acid to Stimulate Deep Wells in Carbonate Reservoirs
Notice bibliographique
Résumé
Abstract Acid treatments in high temperature deep wells drilled in carbonate reservoirs represent a challenge to the oil industry. The high temperature of deep wells requires a special formulation of emulsified acid that can be stable and effective at such high temperatures. At these high temperatures, both the reaction rate between acid and rock, and corrosion rate of tubulars are high. This fact makes protection of tubulars and reducing the reaction rate between rock and acid challenging. At temperatures above 200 °F, there is a need to add more corrosion inhibitor and corrosion inhibitor intensifier, which increases the cost of the treatment too much. A new emulsifier was developed and used to prepare emulsified acids that can be used in stimulating deep wells drilled in carbonate reservoirs. In the present paper, the rheology of the new acid is compared to the rheology of another system formulated by a commercial emulsifier that has been used extensively in the field. All emulsified acid systems were formulated at 0.7 acid volume fraction, and the final HCl concentration varied from 5 to 28 wt% HCl. The rheology measurements were conducted at temperatures up to 300 °F for emulsifier concentration ranges from 0.5 to 2.0 vol%. The reaction between emulsified acid and rock was studied using a rotating disk apparatus at 230 °F and rotation speeds up to 1,500 rpm. A core flood study was conducted in order to study the efficiency of the new emulsified acid to create wormhole, and increase the efficiency of the treatment, especially at a high temperature (300 °F). The results showed that the new emulsified acid system had higher thermal stability and higher viscosity than the old one. Also, the new emulsified acid system created deep wormholes at all injection rates covered (0.1 cm3/min up to 10 cm3/min), with no face dissolution encountered during acid injection. The reaction rate between emulsified acids formulated using the new emulsifier was measured using a rotating disk at 230 °F. The dissolution rate varied between 2.57E-6 gmol/cm2.s at 100 rpm and 1.09E-5 gmol/cm2.s at 1500 rpm. The diffusion rate was measured for these emulsified acid systems and was found to be around 2.73E-7 cm2/s. From these results, the new emulsifier can be used in formulating emulsified acid systems that can be used effectively in stimulation of high temperature deep wells. This paper summarizes the results of testing the new emulsified system, and recommends its use for field application in deep carbonate reservoir.
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Prédiction distillée sur la base complète
Imitation des enseignantsNi prévalence calibrée, ni vérité terrain. Validation humaine à venir. Apprise à partir de 10 348 étiquettes directes de Codex et de 10 348 étiquettes directes de Gemma. Le mode candidate est l'union des têtes enseignantes seuillées; le consensus est leur intersection. Ces sorties portent le statut machine_predicted_unvalidated et ne sont ni des étiquettes humaines ni des étiquettes directes de modèles de pointe.
Scores Codex et Gemma par catégorie
| Catégorie | Codex | Gemma |
|---|---|---|
| Métarecherche | 0,000 | 0,000 |
| Méta-épidémiologie (sens strict) | 0,000 | 0,000 |
| Méta-épidémiologie (sens large) | 0,000 | 0,000 |
| Bibliométrie | 0,000 | 0,000 |
| Études des sciences et des technologies | 0,000 | 0,000 |
| Communication savante | 0,000 | 0,001 |
| Science ouverte | 0,000 | 0,000 |
| Intégrité de la recherche | 0,000 | 0,000 |
| Charge utile insuffisante (le modèle a refusé de juger) | 0,000 | 0,000 |
Scores machine (provisoires)
Les deux têtes enseignantes du modèle étudiant, lues sur ce travail. Un score ordonne la base pour la relecture; il n'affirme jamais une catégorie, et le statut de validation accompagne chaque rangée tel quel.
Scores de référence d'un modèle non mature (critères de maturité non atteints, 7 itérations). Un score ordonne; il n'affirme jamais une catégorie.
score_only:v0-immature-baseline · tel quel depuis la passe de notation : score_only signifie que le nombre peut ordonner les travaux, et qu'aucune étiquette de catégorie n'en découleClassification
machine, non validéePrédiction automatique; un appel candidat d’une seule tête enseignante, pas un consensus.
Le détail, modèle par modèle et score par score, se trouve en fin de page sous « Comment cette classification a été obtenue ».