Fundamental study on extracting lead from cerussite concentrate in methane sulfonic acid based solution
Notice bibliographique
Résumé
Cerussite (PbCO₃) concentrates may be recovered from oxidized lead ores. These concentrates suffer from the intrinsic fuel shortage via traditional smelting route and may lead to widespread contamination in shipment. Therefore, a hydro-electrometallurgical process to treat cerussite concentrate by methane sulfonic acid (MSA) is proposed to solve the above problems. The leaching of cerussite concentrate by MSA was first studied. The parameters of stirring speed, temperature, acid concentration, particle sizes and solid concentration were considered. It was found that stirring speed, temperature, particle size and proton concentration had a significant influence on the kinetics while solid concentration showed no effect on the final lead extraction under the experimental conditions. The leaching results indicated that MSA is favourable to treat cerussite concentrate and the lead extraction could achieve the theoretical maximum in just 10 min at ambient conditions. The lead content in solution obtained at high solid concentration was sufficiently high, and easily met the concentration requirements for the subsequent electrolysis process. After leaching, the residue was subjected to a desulfurization treatment to recover the remaining lead in residue. Using desulfurization agent Na₂CO₃, the remaining lead, mainly in anglesite, was transformed to PbCO₃ that was followed by a re-leaching treatment with MSA. An overall lead recovery of 98% was finally obtained. In the electrowinning process from MSA based electrolyte, the individual and synergistic effects of two ligninsulfonate salts and two glycol-type agents on lead deposit quality were first investigated. Compared to the other three additives, the individual use of calcium ligninsulfonate most benefited the morphology of lead deposit. The operating parameters in the lead electrowinning process (i.e. temperature, current density, concentrations of lead ion and protons) had a widely acceptable range. The cathodic current efficiency and specific energy consumption in most tests were around 99% and 0.53Wh/kg, respectively. The SEM micrographs showed that the lead deposits obtained under the optimal conditions were compact and even. These results for leaching and electrolysis made the MSA system competitive to the comparable fluoborate and fluosilicate systems. Finally a simplified flowsheet to extract lead from cerussite concentrate in MSA based solution was proposed.
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Comment cette classification a été obtenuedéplier
Prédiction distillée sur la base complète
Imitation des enseignantsNi prévalence calibrée, ni vérité terrain. Validation humaine à venir. Apprise à partir de 10 348 étiquettes directes de Codex et de 10 348 étiquettes directes de Gemma. Le mode candidate est l'union des têtes enseignantes seuillées; le consensus est leur intersection. Ces sorties portent le statut machine_predicted_unvalidated et ne sont ni des étiquettes humaines ni des étiquettes directes de modèles de pointe.
Scores Codex et Gemma par catégorie
| Catégorie | Codex | Gemma |
|---|---|---|
| Métarecherche | 0,000 | 0,000 |
| Méta-épidémiologie (sens strict) | 0,000 | 0,000 |
| Méta-épidémiologie (sens large) | 0,000 | 0,000 |
| Bibliométrie | 0,000 | 0,000 |
| Études des sciences et des technologies | 0,000 | 0,000 |
| Communication savante | 0,000 | 0,000 |
| Science ouverte | 0,000 | 0,000 |
| Intégrité de la recherche | 0,000 | 0,000 |
| Charge utile insuffisante (le modèle a refusé de juger) | 0,000 | 0,000 |
Scores machine (provisoires)
Les deux têtes enseignantes du modèle étudiant, lues sur ce travail. Un score ordonne la base pour la relecture; il n'affirme jamais une catégorie, et le statut de validation accompagne chaque rangée tel quel.
Scores de référence d'un modèle non mature (critères de maturité non atteints, 7 itérations). Un score ordonne; il n'affirme jamais une catégorie.
score_only:v0-immature-baseline · tel quel depuis la passe de notation : score_only signifie que le nombre peut ordonner les travaux, et qu'aucune étiquette de catégorie n'en découleClassification
machine, non validéePrédiction automatique; un appel candidat d’une seule tête enseignante, pas un consensus.
Le détail, modèle par modèle et score par score, se trouve en fin de page sous « Comment cette classification a été obtenue ».