Comparison of mineralization of the Sungun and Kighal porphyry copper deposits, NW Iran: with an emphasis on fluid inclusion studies

Introduction Nowadays, more than half of the word’s copper production is obtained from porphyry copper deposits, large (greater than 100 Mt), low- to moderate-grade, disseminated, stockwork-veinlet, carrying at least trace elements, such as molybdenum, gold, and silver (Sillitoe, 1972). Porphyry Cu systems are related to granitoid porphyry intru¬sions and adjacent wall rocks and most of them form at convergent plate margins (John et al., 2010). The deposits are often localized within calc-alkaline porphyry magmatic systems in subduction zone settings. Some PCDs have been formed in post-subduc¬tion settings. Ahar-Arasbaran metallogenic zone is one of the most productive metallogenic zones in Iran. Mineralization in the area is mainly associated with Tertiary magmatic events. In order to perform a comparative study of mineralization, Sungun and Kighal porphyry copper deposits (PCDs) were selected. The Sungun copper deposit is located in the north Varzaqan and the Kighal copper deposit lies 10 km to the south of the Sungun PCD (Calagari, 2003; Calagari, 2004). As recent studies show there are some similarities between the Sungun and Kighal deposits in terms of the parent intrusions, the host rocks, age and geological setting. However, the grade of copper in the Sungun PCD is 0.62 % Cu and in the Kighal PCD is 0.2 % Cu. Therefore, what are the key factors that have made the Kighal PCD sub-economic? Material and methods Geochemical, fluid inclusion, and mineralogical studies were done on collected samples of the two porphyry copper deposits. In order to mineralogically study the Sungun and Kighal PCDs, 100 thin and polished thin sections were prepared. Eleven doubly polished sections of different quartz veins of the two PCD borehole samples were prepared for fluid inclusion studies. The measurements of 205 fluid inclusions were conducted at the Iranian Mineral Processing Research Center (IMPRC) by ZEISS microscope and Linkam TMH600, at temperature limits of -196 to +600 °C. The precision was ±0.6 °C at 414 °C (melting point of Cesium nitrate), and ±2°C at -94.3 (melting point of n-Hexane). SPSS 17 and Flincor computer programs (Brown, 1989) were used for data analysis. Discussion and Results In addition to some similarities of parent intrusions and host rocks (Hassanpour, 2010), there are similar fluid inclusion types and even nearly identical salinity and homogenization temperatures in these deposits (Simmonds, 2013). However, some differences in geochemical and mineralogical features, such as different low zonality index, less sulfide minerals and CO2 contents of the Kighal PCD, are notable. Some researchers have pointed out erosion (Hassanpour, 2010) and uplifting (Simmonds, 2013) as the main reasons for the sub-economic nature of the Kighal (non-productivity), comparison of Moho depth in the two deposits shows a greater crustal thickness in the Sungun PCD area (Fig. 10). The thickness of the lower crust is thought to be critical for governing arc mineralization potential, because it leads to an increase of the amount of water, metal, sulfur in adakitic magma forming arc-related bodies that is known to affect the origin of more productive (economic) porphyry copper deposits. Also low-CO2 fluid inclusions of the Kighal can have originated from a CO2-rich fluid immiscibility at depth (Simmonds, 2013). Lack of CO2 can inhibit (delays) bulk volatile saturation and in turn boiling, which influences the efficiency of metal removal from melt as well (Candela, 1997). CO2 contents of mineralizing fluids is important in increasing of pH during boiling event and ore deposition. The non-productivity of the Kighal PCD may have resulted from all these factors. Acknowledgement This work was supported by Bu-Ali Sina University and Iranian Mines and Mining Industries Development and Renovation Organization (IMIDRO). The authors would like to thank of the Sungun and Ahar copper companies. Special thanks to all the staff for their kind help. Thanks to the reviewers for their suggestions. References Brown, P.E., 1989. FLINCOR; a microcomputer program for the reduction and investigation of fluid-inclusion data. American Mineralogist, 74(11): 1390–1393. Calagari, A.A., 2003. Stable isotope (S, O, H and C) studies of the phyllic and potassic–phyllic alteration zones of the porphyry copper deposit at Sungun, East Azarbaidjan, Iran. Journal of Asian Earth Sciences, 21(7): 767–780. Calagari, A.A., 2004. Fluid inclusion studies in quartz veinlets in the porphyry copper deposit at Sungun, East-Azarbaidjan, Iran. Journal of Asian Earth Sciences, 23(2): 179–189. Candela, P.A., 1997. A review of shallow, ore-related granites: textures, volatiles, and ore metals. Journal of Petrology, 38(12): 1619–1633. Hassanpour, S., 2010. Metallogeney and mineralization of Cu-Au in Arasbaran Zone, NW of Iran. Ph.D. Thesis, Shahid Beheshti University, Tehran, Iran, 320 pp. John, D., Ayuso, R., Barton, M., Blakely, R., Bodnar, R., Dilles, J., Gray, F., Graybeal, F., Mars, J. and McPhee, D., 2010. Porphyry copper deposit model, chap. B of Mineral deposit models for resource assessment, US Geological Survey Scientific Investigations Report, 169 pp. Sillitoe, R.H., 1972. A plate tectonic model for the origin of porphyry copper deposits. Economic geology, 67(2): 184–197. Simmonds, V., Calagari, A.A. and Kyser, K., 2013. Fluid inclusion and stable isotope studies of the Kighal porphyry Cu–Mo prospect, East-Azarbaidjan, NW Iran. Arabian Journal of Geosciences, Fluid inclusion and stable isotope studies of the Kighal porphyry Cu–Mo prospect, East-Azarbaidjan, NW Iran. Arabian Journal of Geosciences, 8(1): 1–17.

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