Quantification of Temperature-Dependent Sorption Isotherms in Shale Gas Reservoirs: Experiment and Theory
Notice bibliographique
Résumé
Summary A critical component of natural gas in organic-rich shales is adsorbed gas within organic matter. Quantification of adsorbed gas is essential for reliable estimates of gas-in-place in shale reservoirs. However, conventional high-pressure adsorption measurements for coal using the volumetric method are prone to error when applied to characterize sorption isotherm in shale gas systems due to limited adsorption capacity and finer pores of shale matrix. Innovative laboratory apparatus and measurement procedures have been developed to accurately determine the relatively small amount of adsorbed gas in a Marcellus shale sample. The custom-built volumetric apparatus is a differential unit composed of two identical single-sided units (one blank and one adsorption side) connected with a differential pressure transducer. The scale of the differential pressure transducer is ±50 psi, a hundred-fold smaller than the absolute pressure transducer measuring to 5,000 psi, leading to a significant increase in the accuracy of adsorption measurement. Methane adsorption isotherms on Marcellus shale are measured at 303, 313, 323, and 333 K with pressure up to 3,000 psi. In addition, a fugacity-based Dubinin-Astakhov (D-A) isotherm is implemented to correct for the nonideality and to predict the temperature dependence of supercritical gas sorption. The Marcellus shale studied generally displays linear correlations between adsorption capacity and pressure over the range of temperature and pressure investigated, indicating the presence of a solute gas component. It is noted that the condensed-phase gas storage exists as the adsorbed gas on the shale surface and dissolved gas in kerogen, where the solute gas amount is proportional to the partial pressure of that gas above the solution. One of the major findings of this work is the experimental observation of the contribution of dissolved gas to total gas storage. With adsorption potential being modeled by a temperature-dependence expression, the D-A isotherm can successfully describe supercritical gas sorption for shale at multiple temperatures. Adsorption capacity significantly decreases with temperature attributed to the isosteric heat of adsorption. Lastly, the broad applicability of the proposed fugacity-based D-A model is also tested for adsorption data provided in the literature for Woodford, Barnett, and Devonian shale. Overall, the fugacity-based D-A isotherm provides precise representations of the temperature-dependent gas adsorption on shales investigated in this work. The application of the proposed adsorption model allows predicting adsorption data at multiple temperatures based on the adsorption data collected at a single temperature. This study lays the foundation for an accurate evaluation of gas storage in shale.
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Prédiction distillée sur la base complète
Imitation des enseignantsNi prévalence calibrée, ni vérité terrain. Validation humaine à venir. Apprise à partir de 10 348 étiquettes directes de Codex et de 10 348 étiquettes directes de Gemma. Le mode candidate est l'union des têtes enseignantes seuillées; le consensus est leur intersection. Ces sorties portent le statut machine_predicted_unvalidated et ne sont ni des étiquettes humaines ni des étiquettes directes de modèles de pointe.
Scores Codex et Gemma par catégorie
| Catégorie | Codex | Gemma |
|---|---|---|
| Métarecherche | 0,001 | 0,000 |
| Méta-épidémiologie (sens strict) | 0,000 | 0,000 |
| Méta-épidémiologie (sens large) | 0,000 | 0,000 |
| Bibliométrie | 0,000 | 0,000 |
| Études des sciences et des technologies | 0,000 | 0,000 |
| Communication savante | 0,000 | 0,000 |
| Science ouverte | 0,000 | 0,000 |
| Intégrité de la recherche | 0,000 | 0,000 |
| Charge utile insuffisante (le modèle a refusé de juger) | 0,001 | 0,000 |
Scores machine (provisoires)
Les deux têtes enseignantes du modèle étudiant, lues sur ce travail. Un score ordonne la base pour la relecture; il n'affirme jamais une catégorie, et le statut de validation accompagne chaque rangée tel quel.
Scores de référence d'un modèle non mature (critères de maturité non atteints, 7 itérations). Un score ordonne; il n'affirme jamais une catégorie.
score_only:v0-immature-baseline · tel quel depuis la passe de notation : score_only signifie que le nombre peut ordonner les travaux, et qu'aucune étiquette de catégorie n'en découleClassification
machine, non validéePrédiction automatique; un appel candidat d’une seule tête enseignante, pas un consensus.
Le détail, modèle par modèle et score par score, se trouve en fin de page sous « Comment cette classification a été obtenue ».