Studies of Si-Fe-C Electrode Materials Prepared By Combinatorial Sputter Deposition
Notice bibliographique
Résumé
Introduction Based on our previous studies (e.g. [1]) and other work [2], it is our opinion that silicon-based amorphous alloys are promising for use as a negative electrode. This is due to the fact that the volume expansion of amorphous silicon (a-Si) upon Li insertion is homogeneous and causes less pulverization as compared to the crystalline material. In addition to the homogenous expansion, the two-phase regions are inhibited once a-Si is used. Herein, a combinatorial study, on Si-Fe-C sputtered films covering a wide range of compositions is presented. The intention is to study the effect of both Fe and C within the electrode on the electrochemical performance. Carbon was added in the hope that some carbon would remain “free” and could transport intercalated Li effectively to the interior of the particles, whereas iron can form an inactive matrix that reduces the overall volume expansion. Experimental Four combinatorial libraries in the Si-Fe-C system were produced using a Corona Vacuum Coaters model V3-T multi-target sputtering system described in [3]. Different targets, two inches in diameter, were used: a Si target, an Fe target and a C target. The targets and a plasma scrubber were mounted on magnetrons. The desired deposition profile was be achieved by using different stationary masks placed over the targets. Figure 1 summarizes the produced compositions. X-ray diffraction was used to study the structure of these libraries and Mossbauer spectroscopy was employed to probe the atomic environment. Cyclic voltammetry measurements were performed using a multichannel pseudopotentiostat to study the behavior of these materials as negative electrodes for Li-ion batteries Results and Discussion Structural Studies: X-ray patterns obtained from all compositions produced in this study were amorphous or nanostructured and no Bragg peaks indicative of any crystalline phases. In order to understand the microstructure, as XRD measurements provide little detailed structural information, room temperature Mössbauer spectroscopy was performed on two libraries denoted by solid triangles and circles. The formation of Si-Fe phases were evident. Electrochemical Analysis: Figure 1(b) shows the potential versus capacity of the library denoted by the solid circles in Figure 1(a). Data for 64 electrode material are shown. Our combinatorial measurement setup allows for a simultaneous and rapid measurement. The impact of adding iron and carbon on the resulting capacity is illustrated clearly in Figure 1(b). Through a combined consideration of Mössbauer effect measurements and electrochemical data, the formation of nanoscale regions of inactive Si-Fe and SiC phases was evident.
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Imitation des enseignantsNi prévalence calibrée, ni vérité terrain. Validation humaine à venir. Apprise à partir de 10 348 étiquettes directes de Codex et de 10 348 étiquettes directes de Gemma. Le mode candidate est l'union des têtes enseignantes seuillées; le consensus est leur intersection. Ces sorties portent le statut machine_predicted_unvalidated et ne sont ni des étiquettes humaines ni des étiquettes directes de modèles de pointe.
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| Catégorie | Codex | Gemma |
|---|---|---|
| Métarecherche | 0,000 | 0,000 |
| Méta-épidémiologie (sens strict) | 0,000 | 0,000 |
| Méta-épidémiologie (sens large) | 0,000 | 0,000 |
| Bibliométrie | 0,000 | 0,000 |
| Études des sciences et des technologies | 0,000 | 0,000 |
| Communication savante | 0,000 | 0,000 |
| Science ouverte | 0,000 | 0,000 |
| Intégrité de la recherche | 0,000 | 0,000 |
| Charge utile insuffisante (le modèle a refusé de juger) | 0,000 | 0,000 |
Scores machine (provisoires)
Les deux têtes enseignantes du modèle étudiant, lues sur ce travail. Un score ordonne la base pour la relecture; il n'affirme jamais une catégorie, et le statut de validation accompagne chaque rangée tel quel.
Scores de référence d'un modèle non mature (critères de maturité non atteints, 7 itérations). Un score ordonne; il n'affirme jamais une catégorie.
score_only:v0-immature-baseline · tel quel depuis la passe de notation : score_only signifie que le nombre peut ordonner les travaux, et qu'aucune étiquette de catégorie n'en découleClassification
machine, non validéePrédiction automatique; un appel candidat d’une seule tête enseignante, pas un consensus.
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