Separation of Praseodymium and Neodymium from Heavy Rare Earth Elements Using Extractant-Impregnated Surfaces Loaded with 2-Ethylhexyl Phosphonic Acid-mono-2-ethylhexyl Ester (PC88A)
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Résumé
In the rare earth industry, the next step after leaching and impurity removal is separation. The most common technology for separation is solvent extraction. Although promising, it faces a few challenges including the large consumption of organic solvents, large volumes of waste generation, and the need for multiple stages to achieve the desired separation factor. An alternative approach to solvent extraction is supported-liquid extraction (SLE) in which the extractant phase is supported in place by a solid support media in which the liquid extraction takes place. The main advantages of SLE over solvent extraction are lower solvent consumption and less generation of hazardous waste. Here, an extractant-impregnated surface (EIS) made of a microtextured silicon substrate coated with octadecyltrichlorosilane for hydrophobicity and impregnated with 2-ethylhexyl phosphonic acid-mono-2-ethylhexyl ester (PC88A) is developed to separate praseodymium and neodymium from a mixture of heavy rare earth elements. The possible contact modes including impaled, impregnated, and encapsulated are investigated, and it is found that the impregnated mode can be achieved when 0 < θ es(w) < θ c . The feed contains 10 mg/L of all REEs at pH 2.5. The key separation performance indicators including yield, purity, and separation factor are determined, and the results indicate that the final praseodymium + neodymium purity is 92% with 96% yield, and a separation factor of 171 that is comparable with solvent extraction is achieved. Kinetic studies indicate that the pseudo-second-order kinetic model fits the kinetic data, which means that the adsorption is controlled by chemisorption with an activation energy of 69.3 kJ mol –1 . Thermodynamic studies indicate that the adsorption process of the studied REEs on PC88A-EIS is endothermic (Δ H ads = 31.3 kJ/mol). The Gibbs free energy of praseodymium and neodymium is positive, whereas that of heavy rare earth elements is negative (−8.56 kJ/mol), indicating that the heavy rare earth elements’ adsorption on PC88A is spontaneous whereas that of praseodymium and neodymium is not spontaneous. Therefore, the system can selectively separate heavy rare earths over praseodymium and neodymium. Isotherm studies indicate that the Langmuir model better fits the adsorption data, suggesting that the monolayer homogeneous adsorption mechanism is the controlling mechanism. The maximum heavy rare earths’ adsorption amount was found to be 671.4 mg/cm 2, which is comparable to those obtained using functionalized adsorbents. The adsorbed heavy rare earths were eluted with 4.5 M H 2 SO 4, and the EIS was regenerated and reused for several cycles, indicating a cost-effective potential material in real applications.
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Imitation des enseignantsNi prévalence calibrée, ni vérité terrain. Validation humaine à venir. Apprise à partir de 10 348 étiquettes directes de Codex et de 10 348 étiquettes directes de Gemma. Le mode candidate est l'union des têtes enseignantes seuillées; le consensus est leur intersection. Ces sorties portent le statut machine_predicted_unvalidated et ne sont ni des étiquettes humaines ni des étiquettes directes de modèles de pointe.
Scores Codex et Gemma par catégorie
| Catégorie | Codex | Gemma |
|---|---|---|
| Métarecherche | 0,001 | 0,000 |
| Méta-épidémiologie (sens strict) | 0,000 | 0,000 |
| Méta-épidémiologie (sens large) | 0,000 | 0,000 |
| Bibliométrie | 0,000 | 0,001 |
| Études des sciences et des technologies | 0,000 | 0,000 |
| Communication savante | 0,000 | 0,001 |
| Science ouverte | 0,000 | 0,000 |
| Intégrité de la recherche | 0,000 | 0,001 |
| Charge utile insuffisante (le modèle a refusé de juger) | 0,000 | 0,000 |
Scores machine (provisoires)
Les deux têtes enseignantes du modèle étudiant, lues sur ce travail. Un score ordonne la base pour la relecture; il n'affirme jamais une catégorie, et le statut de validation accompagne chaque rangée tel quel.
Scores de référence d'un modèle non mature (critères de maturité non atteints, 7 itérations). Un score ordonne; il n'affirme jamais une catégorie.
score_only:v0-immature-baseline · tel quel depuis la passe de notation : score_only signifie que le nombre peut ordonner les travaux, et qu'aucune étiquette de catégorie n'en découle