Characterization and acid treatment of silica and organics in evaporator blowdown wastewater arising from SAGD operations
Notice bibliographique
Résumé
The evaporator blowdown (EBD) wastewater from high-pressure steam generation for the steam-assisted gravity drainage (SAGD) bitumen extraction process contains elevated concentrations of dissolved inorganic and organic compounds, of which silica and organics pose challenges in its treatment and disposal. This study investigated treatment options for EBD before its disposal. Following detailed physical and chemical characterization of the EBD, we examined its acid treatment with HCl and H 2 SO 4 at pHs ranging from 12 to 2. The acid treatment performance was evaluated in terms of silica and organic removal efficiencies along with the filtration rate and filtrate recovery. Both acids gave similar silica and organic removal efficiencies; however, the filtration performance following the HCl-treatment was better than the H 2 SO 4 -treatment. In practice, the acids would likely perform comparably with regard to silica removal and the final process selection would more likely be influenced by other factors such as storage, material compatibility, cost, and downstream or subsurface compatibility. The HCl-treatment was investigated further with both the EBD and prepared silica solutions for the silica removal efficiency and filtration performance. The experiments conducted at ∼20 °C demonstrated higher silica removal efficiencies at pHs 10 and 8, whereas higher organic removal efficiencies were obtained at pHs 4 and 2. The experiments conducted at ∼80 °C showed enhanced silica removal at pH = 8 and higher organic removal at pH = 2. The precipitated solids were characterized using XRD and ATR-FTIR spectroscopy to identify the minerals and functional groups. The XRD patterns demonstrated that the solids generated were amorphous. The ATR-FTIR spectra revealed the predominance of siloxane, silanol, carboxylate and carbonyl compounds. These results confirmed a substantial removal of silica and organic constituents from the EBD through the acid treatment process. • An in-depth characterization of the constituents in the evaporator blowdown wastewater from SAGD bitumen extraction operations. • The effects of pH, acid-type, and temperature investigated for filtrate recovery, filtration rate, silica, and organic removal efficiencies. • An elaborate characterization of the precipitated solids carried out, using XRD, ATR-FTIR, CHNS, and XRF techniques. • pH and temperature identified as parameters for the efficiency of silica and organic removal in evaporator blowdown wastewater.
Récupéré en direct depuis OpenAlex et désinversé. Les résumés ne sont pas conservés dans cette base de données : les index inversés représentent 8,6 Go des 9,3 Go de texte de la base, et le serveur dispose de 13 Go libres.
Comment cette classification a été obtenuedéplier
Prédiction distillée sur la base complète
Imitation des enseignantsNi prévalence calibrée, ni vérité terrain. Validation humaine à venir. Apprise à partir de 10 348 étiquettes directes de Codex et de 10 348 étiquettes directes de Gemma. Le mode candidate est l'union des têtes enseignantes seuillées; le consensus est leur intersection. Ces sorties portent le statut machine_predicted_unvalidated et ne sont ni des étiquettes humaines ni des étiquettes directes de modèles de pointe.
Scores Codex et Gemma par catégorie
| Catégorie | Codex | Gemma |
|---|---|---|
| Métarecherche | 0,000 | 0,000 |
| Méta-épidémiologie (sens strict) | 0,000 | 0,000 |
| Méta-épidémiologie (sens large) | 0,000 | 0,000 |
| Bibliométrie | 0,000 | 0,000 |
| Études des sciences et des technologies | 0,000 | 0,000 |
| Communication savante | 0,000 | 0,000 |
| Science ouverte | 0,000 | 0,000 |
| Intégrité de la recherche | 0,000 | 0,000 |
| Charge utile insuffisante (le modèle a refusé de juger) | 0,000 | 0,000 |
Scores machine (provisoires)
Les deux têtes enseignantes du modèle étudiant, lues sur ce travail. Un score ordonne la base pour la relecture; il n'affirme jamais une catégorie, et le statut de validation accompagne chaque rangée tel quel.
Scores de référence d'un modèle non mature (critères de maturité non atteints, 7 itérations). Un score ordonne; il n'affirme jamais une catégorie.
score_only:v0-immature-baseline · tel quel depuis la passe de notation : score_only signifie que le nombre peut ordonner les travaux, et qu'aucune étiquette de catégorie n'en découleClassification
machine, non validéePrédiction automatique; un appel candidat d’une seule tête enseignante, pas un consensus.
Le détail, modèle par modèle et score par score, se trouve en fin de page sous « Comment cette classification a été obtenue ».