Active and passive sampling techniques in headwater streams to characterize acesulfame-K, pharmaceutical and phosphorus contamination from on-site wastewater disposal systems in Canadian rural hamlets
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Notice bibliographique
Résumé
On-site wastewater disposal systems have been identified as a source of contamination for nutrients and emerging contaminants (ECs), such as artificial sweeteners and pharmaceutical compounds. The passive sampling technique Polar Organic Chemical Integrative Sampler (POCIS) and phosphorus sampler (P-Trap) have been widely used for tracking polar organic contaminants and total dissolved phosphorus in environmental waters such as surface water and wastewater. However, limited studies have been conducted on application of passive sampling techniques to track contamination in headwater streams impacted by on-site wastewater disposal systems. In this study, active sampling (discrete samples) and passive sampling (P-Trap and POCIS) techniques were applied in upstream and downstream locations at three rural hamlets to compare and track the contamination of total dissolved phosphorus (TDP) and seven ECs, including six pharmaceuticals and one artificial sweetener acesulfame-K (ACE-K), in the shallow headwater streams of rural hamlets in southern Ontario, Canada that exclusively rely on septic systems for wastewater disposal. Results show that POCIS and P-Trap yielded comparable time-weighted average (TWA) concentrations of target ECs and TDP, respectively, to mean concentrations of discrete samples during the seasonal (spring, summer, and fall) and two-week intensive study periods. Field-derived sampling rates ( R s - field ) of target contaminants compared well to literature-reported values indicating POCIS and P-Trap were applicable in determining the concentrations of target contaminants in the investigated streams, even though some environmental factors, such as dry stream conditions and fouling, occurred during the sampling period. The low but stable R s - field of ACE-K (∼0.001 L d −1 ) from this study indicates consistency in application of POCIS for capturing ACE-K. The results of this study provide insight into the confidence and limitations for using POCIS and P-traps to track ECs and TDP in shallow headwater streams impacted by septic systems. • Discrete and passive sampling showed target pollutants downstream of septic systems. • Good agreement between discrete and passive sampling results for target pollutants • Field-derived R s values determined for ACE-K and six pharmaceuticals • Environmental factors, such as biofouling can affect uptake on passive samplers. • POCIS with HLB sorbents is applicable to sample ACE-K with low but stable R s .
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Prédiction distillée sur la base complète
Imitation des enseignantsNi prévalence calibrée, ni vérité terrain. Validation humaine à venir. Apprise à partir de 10 348 étiquettes directes de Codex et de 10 348 étiquettes directes de Gemma. Le mode candidate est l'union des têtes enseignantes seuillées; le consensus est leur intersection. Ces sorties portent le statut machine_predicted_unvalidated et ne sont ni des étiquettes humaines ni des étiquettes directes de modèles de pointe.
Scores Codex et Gemma par catégorie
| Catégorie | Codex | Gemma |
|---|---|---|
| Métarecherche | 0,000 | 0,000 |
| Méta-épidémiologie (sens strict) | 0,000 | 0,000 |
| Méta-épidémiologie (sens large) | 0,000 | 0,000 |
| Bibliométrie | 0,000 | 0,000 |
| Études des sciences et des technologies | 0,000 | 0,001 |
| Communication savante | 0,000 | 0,000 |
| Science ouverte | 0,000 | 0,000 |
| Intégrité de la recherche | 0,000 | 0,000 |
| Charge utile insuffisante (le modèle a refusé de juger) | 0,000 | 0,000 |
Scores machine (provisoires)
Les deux têtes enseignantes du modèle étudiant, lues sur ce travail. Un score ordonne la base pour la relecture; il n'affirme jamais une catégorie, et le statut de validation accompagne chaque rangée tel quel.
Scores de référence d'un modèle non mature (critères de maturité non atteints, 7 itérations). Un score ordonne; il n'affirme jamais une catégorie.
score_only:v0-immature-baseline · tel quel depuis la passe de notation : score_only signifie que le nombre peut ordonner les travaux, et qu'aucune étiquette de catégorie n'en découle