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Record W109096723 · doi:10.31274/rtd-180813-8773

Soybean-based wood adhesives for structural panels

2002· dissertation· en· W109096723 on OpenAlexaboutno aff
In Yang

Bibliographic record

Venuenot available
Typedissertation
Languageen
FieldEngineering
TopicLignin and Wood Chemistry
Canadian institutionsnot available
Fundersnot available
KeywordsAdhesiveEngineered woodGLUEMaterials scienceCuring (chemistry)Soy flourBond strengthComposite materialExtenderSoftwoodPulp and paper industryChemistryFood sciencePolyurethane

Abstract

fetched live from OpenAlex

Recent research attention has focused on soybean-based adhesives because of increased phenolic resin prices and adhesive demand. This study was conducted to investigate the adhesive properties of crosslinked soy flour and/or soy hydrolyzate with phenol-formaldehyde (PF) resins for use in structural panels. Neutral phenolic soy (NPS) and alkaline phenolic soy (APS) resins were prepared and used to bond southern pine plywood. Adhesive bond quality of the soybean-based phenolic resins was evaluated by glueline shear test following the procedure detailed in Product Standard PS 1-95 for construction and industrial plywood. Within the range of variable levels investigated, the following conditions produced higher wet wood failure than a control glue mix. For NPS resins best results were obtained with a 160 cps PF, a 30 minute assembly time, and no extender. For APS resins best results were obtained with a 50 cps PF, a 200°C press temperature, 19% corn-cob powder, and a 60 minute assembly time. Comparable results were obtained with either a 40% or 50% PF level in the resins. Under these conditions, the wet wood failure of plywood bonded with both resins approached the requirement of PS 1-95 for construction and industrial plywood. The APS resins were also used to fabricate homogeneous hybrid poplar flakeboards with different resin solid levels (5%, 7%, and 9%), press temperatures (175 and 200°C), and press times of 8 and 10 minutes. Internal bond strength, wet modulus of rupture, and dimensional stabilities of flakeboard improved with increased press time, press temperature, and PF level in the resins. In particular, increased press time can be used to offset the poor internal bonding associated with high resin content and the excessive moisture present in the mat. However, APS resin-bonded flakeboards provided higher mechanical and better dimensional stability properties compared to the Canadian Standard Association O437 standard, except for modulus of elasticity, which could be easily improved by flake alignment. Optimum production condition for flakeboard bonded with the APS resins are a 5% resin level, a 50% PF level, a 200°C press temperature, and an 8 minute press time. Although NPS and APS resins can be competitive with other conventional adhesives, further improvements are required to reduce press times for industrial applications.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.003
Threshold uncertainty score0.009

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0030.001

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.012
GPT teacher head0.229
Teacher spread0.218 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations1
Published2002
Admission routes1
Has abstractyes

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