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Record W147432407 · doi:10.5006/c2004-04382

Prediction for CO2 Corrosion of Active Steel under a Precipitate

2004· article· en· W147432407 on OpenAlexaff
F.M. Song, Donald W. Kirk, J. W. Graydon, D. E. Cormack

Bibliographic record

Venuenot available
Typearticle
Languageen
FieldEngineering
TopicConcrete Corrosion and Durability
Canadian institutionsUniversity of Toronto
Fundersnot available
KeywordsCorrosionMaterials scienceMetallurgy

Abstract

fetched live from OpenAlex

Abstract This paper presents a convenient deterministic CO2 corrosion model which encapsulates CO2 dissolution, hydration, diffusion, H2CO3 formation and dissociation, local ionic interactions, FeCO3 precipitation and electrochemical (anodic and cathodic) reactions at the steel surface. Good agreement between the model results and a variety of published experimental data is shown under both FeCO3- saturated and unsaturated solution boundary layers. From a theoretical point of view and in a quantitative manner, the model revealed that the steel corrosion in carbonic acid is more severe than in hydrochloric acid for the same pH, due to H2CO3 reduction. Also shown is that as temperature increases, the corrosion rate increases substantially. This model allows for a reliable CO2 corrosion prediction for steels being used in petroleum production and gas transportation systems. This model in its current form is not fully applicable for steel surfaces either dry or covered with a real passive scale.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.249
Threshold uncertainty score0.262

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.022
GPT teacher head0.229
Teacher spread0.207 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations8
Published2004
Admission routes1
Has abstractyes

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