Cathodic Contact Glow Discharge Electrolysis for the Degradation of Liquid Ammonia Solutions
Bibliographic record
Abstract
The application of 50 VDC cathodic contact glow discharge electrolysis for six hours in 1.0 mol/L KOH + 0.8, 0.4 and 0.08 g/L ammonia results in the removal of 66, 71 and 77% of ammonia, respectively, following pseudo first‐order kinetics at ca. 0.3 mol/kWh. The yields of dissolved NO2N and NO3N lie between 9 and 29% and are coupled with ammonia removal suggesting a nitrification process. Based on the near‐cathode UV–Vis emissions and ionization products of H2O and NH3 molecules, a mechanism is proposed along with the charge/energy transfer reactions between the plasma‐generated free radicals and ionic species. Joule heating and vaporization are also believed to physically remove ammonia.
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How this classification was reachedexpand
Full frame machine prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.
Distilled classifier scores by category (both heads)
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.001 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".