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Record W1487957956 · doi:10.1002/chin.201426019

ChemInform Abstract: Noble‐Gas Difluoride Complexes of Mercury(II): The Syntheses and Structures of Hg(OTeF<sub>5</sub>)<sub>2</sub>·1.5NgF<sub>2</sub> (Ng: Xe, Kr) and Hg(OTeF<sub>5</sub>)<sub>2</sub>.

2014· article· en· W1487957956 on OpenAlexaff
John R. De Backere, Hélène P. A. Mercier, Gary J. Schrobilgen

Bibliographic record

VenueChemInform · 2014
Typearticle
Languageen
FieldChemistry
TopicInorganic Fluorides and Related Compounds
Canadian institutionsMcMaster University
Fundersnot available
KeywordsChemistryMercury (programming language)DifluorideNoble gasRaman spectroscopySolid-stateSpectroscopyXenon difluorideNuclear magnetic resonance spectroscopyPhysical chemistryCrystallographyInorganic chemistryAnalytical Chemistry (journal)StereochemistryOrganic chemistry

Abstract

fetched live from OpenAlex

Abstract The structures of (III) and (V) are characterized in the solid state by Raman spectroscopy and single crystal XRD, and in solution by 19 F NMR spectroscopy for (III).

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.002
metaresearch head score (Gemma)0.001
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow), Science and technology studies, Research integrity
Consensus categoriesMeta-epidemiology (narrow), Science and technology studies, Research integrity
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.143
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0020.001
Meta-epidemiology (narrow)0.0030.003
Meta-epidemiology (broad)0.0040.001
Bibliometrics0.0010.001
Science and technology studies0.0020.003
Scholarly communication0.0010.002
Open science0.0030.002
Research integrity0.0030.004
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.008
GPT teacher head0.200
Teacher spread0.192 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; both teacher heads agree on what is shown here.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2014
Admission routes1
Has abstractyes

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