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Record W1498165882 · doi:10.1107/s1600536809036708

<i>N</i><sup>1</sup>,<i>N</i><sup>2</sup>-Bis(2,6-dimethylphenyl)-<i>N</i><sup>1</sup>-hydroxyformamidine<i>N</i>,<i>N</i>′-bis(2,6-dimethylphenyl)-<i>N</i>-oxidoformamidinium dichloromethane solvate

2009· article· he· W1498165882 on OpenAlexaff
Mihaela Cibian, S. Derossi, Garry S. Hanan

Bibliographic record

VenueActa Crystallographica Section E Structure Reports Online · 2009
Typearticle
Languagehe
FieldChemistry
TopicQuinazolinone synthesis and applications
Canadian institutionsUniversité de Montréal
Fundersnot available
KeywordsDimerBenzoic acidChemistryMedicinal chemistryHydrogen bondCrystallographyMoleculeOrganic chemistry

Abstract

fetched live from OpenAlex

The title compound, 2C(17)H(20)N(2)O·CH(2)Cl(2), was obtained by N-oxidation of the parent formamidine with m-chloro-peroxy-benzoic acid (m-CPBA). This is the first use of the above-mentioned synthetic route for the preparation of hydroxy-amidines. The title compound crystallizes as a cyclic dimer resulting from the presence of O-H⋯O and N-H⋯N hydrogen bonds.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.005
metaresearch head score (Gemma)0.002
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow), Science and technology studies, Scholarly communication, Open science, Research integrity, Insufficient payload (model declined to judge)
Consensus categoriesMeta-epidemiology (narrow), Science and technology studies, Research integrity
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Not applicable · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.853
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0050.002
Meta-epidemiology (narrow)0.0090.009
Meta-epidemiology (broad)0.0090.006
Bibliometrics0.0050.013
Science and technology studies0.0050.003
Scholarly communication0.0020.005
Open science0.0060.002
Research integrity0.0080.012
Insufficient payload (model declined to judge)0.0070.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.009
GPT teacher head0.241
Teacher spread0.231 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; both teacher heads agree on what is shown here.

Study designNot applicable
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations4
Published2009
Admission routes1
Has abstractyes

Explore more

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