Copolymerization of Limonene with <i>n</i>‐Butyl Acrylate
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Bibliographic record
Abstract
The bulk free radical copolymerization of d‐limonene (Lim) with n ‐butyl acrylate (BA) was carried out at 80 °C using benzoyl peroxide as initiator. Low conversion experiments were run to estimate the copolymer reactivity ratios as r BA = 6.07 and r Lim = 0.0067. High conversion experiments were then conducted to validate the reactivity ratios for prediction of cumulative copolymer composition. The presence of allylic hydrogen in d‐limonene caused a notable degradative chain transfer reaction which greatly impeded polymerization. Increasing d‐limonene fractions in the copolymer resulted in a decrease in final conversion and molecular weight, and an increase in glass transition temperature.
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Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it