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Record W1535867659 · doi:10.1017/cbo9780511781292.005

Disorders of hemoglobin synthesis

2011· book-chapter· en· W1535867659 on OpenAlexaff
Alexander Kratz, Jeffrey S. Jhang

Bibliographic record

VenueCambridge University Press eBooks · 2011
Typebook-chapter
Languageen
FieldMedicine
TopicHemoglobinopathies and Related Disorders
Canadian institutionsColumbia College
Fundersnot available
KeywordsTetramerHemoglobinChemistryGlobinHemeOxygen transportHemeproteinMoleculeOxygenRing (chemistry)StereochemistryBiochemistryOrganic chemistry

Abstract

fetched live from OpenAlex

Normal hemoglobins Structure and function of hemoglobin Hemoglobin consists of two alpha-like and two beta-like globin chains which combine to form a tetramer. The globin tetramer is hydrophilic on its surface, making the molecule water soluble. The center is hydrophobic, stabilizing the heme ring and the iron molecule in the ferrous state (Fe 2+ ). Located in the interior of each globin chain is a heme ring with an iron molecule in the center. It is in the heme ring that oxygen binding and release take place. In addition to oxygen transport, hemoglobin also plays a minor role in the transport of carbon dioxide, and as a scavenger of nitric oxide (NO). As the partial pressure of oxygen is increased, hemoglobin becomes saturated with oxygen. The partial pressure at which 50% of hemoglobin is saturated is called the p50. Normal subjects have a p50 between 23 and 27 mmHg. Binding of an oxygen molecule in one heme changes the tetrameric structure so that additional oxygen molecules are bound with greater ease; this property of hemoglobin is called cooperativity, and is dependent on interactions between the globin chains (“heme–heme interaction”). The oxygen dissociation curve for hemoglobin A is sigmoid shaped because of this cooperativity (Fig. 4.1) [1, 2]. The sigmoid shape reflects how oxygen binding is favored at high oxygen tensions (lungs) and is rapidly released at low oxygen tensions (tissues).

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.001
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Not applicable · Consensus signal: none
GenreCandidate signal: Other · Consensus signal: none
Teacher disagreement score0.011
Threshold uncertainty score0.038

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.001
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0010.001
Science and technology studies0.0000.001
Scholarly communication0.0010.000
Open science0.0000.001
Research integrity0.0000.001
Insufficient payload (model declined to judge)0.0110.003

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.015
GPT teacher head0.189
Teacher spread0.174 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designNot applicable
Domainnot available
GenreOther

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations4
Published2011
Admission routes1
Has abstractyes

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Same venueCambridge University Press eBooksSame topicHemoglobinopathies and Related DisordersFrench-language works237,207