Chalcogenide Derivatives of the <i>seco</i>‐Cubane [Sn<sub>3</sub>(<i>μ</i><sub>2</sub>‐NH<i>t</i>Bu)<sub>2</sub>(<i>μ</i><sub>2</sub>‐N<i>t</i>Bu)(<i>μ</i><sub>3</sub>‐N<i>t</i>Bu)]
Why this work is in the frame
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Bibliographic record
Abstract
Abstract A series of monochalcogenide derivatives of the seco ‐cubane [Sn 3 ( μ 2 ‐NH t Bu) 2 ( μ 2 ‐N t Bu)( μ 3 ‐N t Bu)] has been prepared and characterized by NMR and X‐ray crystallographic studies. These complexes exhibit different tin‐chalcogen bonding modes. In the case of the monotelluride, a terminal Sn=Te bond was observed in solution and in the solid state, whereas for the monosulfide, a μ 2 bridging mode was adopted by the sulfur atoms. The monoselenide was found to employ both bonding modes in solution, although only the terminal Sn=Se bonding mode was structurally characterized. The complexes undergo chalcogen exchange between tin atoms in solution, and this process was studied by variable temperature NMR.
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Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.002 | 0.002 |
| Meta-epidemiology (narrow) | 0.006 | 0.006 |
| Meta-epidemiology (broad) | 0.006 | 0.004 |
| Bibliometrics | 0.001 | 0.006 |
| Science and technology studies | 0.003 | 0.003 |
| Scholarly communication | 0.001 | 0.003 |
| Open science | 0.006 | 0.004 |
| Research integrity | 0.003 | 0.005 |
| Insufficient payload (model declined to judge) | 0.000 | 0.002 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it