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Helium Group Compounds

2000· other· en· W1564740914 on OpenAlexaff
Gary J. Schrobilgen, J. Marc Whalen

Bibliographic record

VenueKirk-Othmer Encyclopedia of Chemical Technology · 2000
Typeother
Languageen
FieldChemistry
TopicInorganic Fluorides and Related Compounds
Canadian institutionsMcMaster University
Fundersnot available
KeywordsKryptonXenonChemistryFluorineNoble gasOxygenNeonPhysical chemistryOrganic chemistryArgon

Abstract

fetched live from OpenAlex

Abstract Compounds of the helium‐group gases, known since 1962, are limited to those of xenon, krypton, and radon. These heavy noble gases form stable compounds and adducts with fluorine and other powerful oxidants. Xenon has the best studied, most extensive chemistry. The oxidation states observed for xenon range from \documentclass{article}\pagestyle{empty}\begin{document}${+}$\end{document} to \documentclass{article}\pagestyle{empty}\begin{document}${+8}$\end{document} . Bonds to fluorine, oxygen, nitrogen, and carbon have been characterized. The chemistry of krypton, which has one known oxidation state, \documentclass{article}\pagestyle{empty}\begin{document}${+2}$\end{document} , is far less extensive, but bonds to fluorine, oxygen, and nitrogen have been characterized. That of radon is even less well characterized and is limited to fluoride species of the \documentclass{article}\pagestyle{empty}\begin{document}${+2}$\end{document} oxidation state. Properties of the compounds are reviewed.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow), Research integrity, Insufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Not applicable · Consensus signal: Not applicable
GenreCandidate signal: Other · Consensus signal: Other
Teacher disagreement score0.186
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0010.001
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0010.001
Science and technology studies0.0000.001
Scholarly communication0.0000.000
Open science0.0010.000
Research integrity0.0040.002
Insufficient payload (model declined to judge)0.0150.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.004
GPT teacher head0.202
Teacher spread0.198 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designNot applicable
Domainnot available
GenreOther

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2000
Admission routes1
Has abstractyes

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