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Record W1574533543 · doi:10.1002/0471484237.ch5

The Momentum Density Perspective of the Electronic Structure of Atoms and Molecules

2003· other· en· W1574533543 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.

Bibliographic record

VenueAdvances in chemical physics · 2003
Typeother
Languageen
FieldChemistry
TopicAdvanced Physical and Chemical Molecular Interactions
Canadian institutionsUniversity of New Brunswick
Fundersnot available
KeywordsPosition and momentum spaceMomentum (technical analysis)Atoms in moleculesElectronWave functionPhysicsSymmetry (geometry)Space (punctuation)MoleculePosition (finance)Atomic physicsChemistryQuantum mechanicsMathematicsGeometry

Abstract

fetched live from OpenAlex

This article surveys electron momentum densities of atoms and molecules. The connections among the position- and momentum-space representations of wave functions and reduced density matrices, electron number (or charge) and momentum densities, and related quantities are outlined. General properties of momentum densities, including symmetry, expansion methods, asymptotic behavior and moments, are described. Experimental and computational methods for obtaining momentum densities are reviewed. A sample of representative work on the electron momentum densities of specific atoms and molecules is summarized. An extensive, but non-exhaustive, bibliography is provided.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: none
Teacher disagreement score0.753
Threshold uncertainty score0.625

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.001
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.001
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.002
GPT teacher head0.237
Teacher spread0.235 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it