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Record W1576695489 · doi:10.1002/9780470027318.a0869

Solid‐Phase Microextraction in Environmental Analysis

2000· other· en· W1576695489 on OpenAlexaff
Janusz Pawliszyn

Bibliographic record

VenueEncyclopedia of Analytical Chemistry · 2000
Typeother
Languageen
FieldChemistry
TopicAnalytical chemistry methods development
Canadian institutionsUniversity of Waterloo
Fundersnot available
KeywordsSolid-phase microextractionAnalyteSorbentSample preparationChromatographyMatrix (chemical analysis)CoatingComplex matrixMaterials scienceExtraction (chemistry)Solid phase extractionAnalytical Chemistry (journal)AdsorptionChemistryNanotechnologyGas chromatography–mass spectrometryMass spectrometryOrganic chemistry

Abstract

fetched live from OpenAlex

Abstract Solid‐phase microextraction (SPME) uses a small volume of sorbent dispersed typically on a surface of small fibers to isolate and concentrate analytes from a sample matrix. After contact with the sample, analytes are absorbed or adsorbed by the fiber phase (depending on the nature of the coating) until an equilibrium is reached in the system. The amount of an analyte extracted by the coating at equilibrium is determined by the magnitude of the partition coefficient of the analyte between the sample matrix and the coating material. After the extraction step, the fibers are transferred, with the help of the syringe‐like handling device, to an analytical instrument, for separation and quantitation of target analytes. This technique is able to integrate sampling, extraction and sample introduction in a simple way, facilitating on‐site monitoring. The additional advantages include elimination of solvents from the sample preparation step and convenient introduction of extracted components into the analytical instrument. Applications of this technique to date include environmental, industrial hygiene, process monitoring, clinical, forensic, food and flavor, fragrance and drugs, in laboratory and on‐site analysis.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow), Insufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Not applicable · Consensus signal: Not applicable
GenreCandidate signal: Other · Consensus signal: Other
Teacher disagreement score0.222
Threshold uncertainty score0.999

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0010.001
Meta-epidemiology (broad)0.0020.001
Bibliometrics0.0000.001
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0010.000
Research integrity0.0010.001
Insufficient payload (model declined to judge)0.1560.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.010
GPT teacher head0.310
Teacher spread0.300 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designNot applicable
Domainnot available
GenreOther

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations4
Published2000
Admission routes1
Has abstractyes

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