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Record W1597161368 · doi:10.1002/9781118495247.ch2

Stationary Phases for Hilic

2013· other· en· W1597161368 on OpenAlexafffund
Mohammed Ibrahim, Charles A. Lucy

Bibliographic record

Venuenot available
Typeother
Languageen
FieldChemistry
TopicAnalytical Chemistry and Chromatography
Canadian institutionsAlberta Glycomics CentreUniversity of Alberta
FundersNatural Sciences and Engineering Research Council of Canada
KeywordsHydrophilic interaction chromatographyChemistryStationary phaseChromatographySelectivityHigh-performance liquid chromatographyOrganic chemistry

Abstract

fetched live from OpenAlex

Literature and research on hydrophilic interaction liquid chromatography (HILIC) has increased dramatically in recent years. This has been accompanied by a correspondingly rapid increase in stationary phases developed for HILIC. This chapter first discusses all classes of stationary phases used in HILIC mode in terms of chemistry, available trade names, and representative applications. The classes of stationary phases include underivatized silica phase, derivatized silica phase, and nonsilica phases. Important characteristics of some selected commercial HILIC phases are summarized in a table. The table classifies HILIC phases according to their chemical nature. Then, the chapter compares these HILIC phases in terms of efficiency, retention, and selectivity.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.001
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Not applicable · Consensus signal: none
GenreCandidate signal: Other · Consensus signal: none
Teacher disagreement score0.043
Threshold uncertainty score0.143

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0010.001
Meta-epidemiology (narrow)0.0020.001
Meta-epidemiology (broad)0.0010.001
Bibliometrics0.0030.002
Science and technology studies0.0010.001
Scholarly communication0.0010.002
Open science0.0010.001
Research integrity0.0010.003
Insufficient payload (model declined to judge)0.0430.067

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.011
GPT teacher head0.249
Teacher spread0.238 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designNot applicable
Domainnot available
GenreOther

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations8
Published2013
Admission routes2
Has abstractyes

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