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Record W1606444741 · doi:10.5539/mas.v9n7p47

Development of Hybrid Fischer-Tropsch Synthesis Catalysts for Direct Production of Synthetic Gasoline from Coal-Based Syngas: An Indonesian Perspective

2015· article· en· W1606444741 on OpenAlexvenueno aff
Donny Satria Bhuana, Junshe Zhang, Fanxing Li, Matthew Cooper, Timothy Brantley

Bibliographic record

VenueModern Applied Science · 2015
Typearticle
Languageen
FieldChemical Engineering
TopicCatalysts for Methane Reforming
Canadian institutionsnot available
FundersDirektorat Jenderal Pendidikan Tinggi
KeywordsFischer–Tropsch processProduct distributionCatalysisSyngasZeoliteGasolineChemical engineeringCoalHydrocarbonMaterials scienceChemistryOrganic chemistrySelectivity

Abstract

fetched live from OpenAlex

The Fischer-Tropsch Synthesis (FTS) represents an environmentally friendly method for producing liquid fuelfrom coal-based syngas via the hydrogenation of carbon monoxide. In order for such a process to be feasible,better catalysts that are capable of enhancing the reaction performance are required. In response to these needs,new catalysts were investigated and introduced in this work. The incorporation of zeolite into the iron based FTScatalyst was expected to help refine the hydrocarbon products and shift the product distribution from the typicalFTS product range to the middle iso-paraffins, which is a gasoline range, and eventually increase the yield of theliquid fuel. This study aims to develop catalyst for producing liquid fuel, particularly gasoline, from carbonmonoxide and hydrogen. The pH of the catalysts was found to have significant effect on the catalytic activity dueto its ability to control the amount of promoter to be precipitated in the catalyst, which results in a lowerreduction temperature. Physically mixing the iron based FTS catalyst with zeolite was found to have little effecton the catalytic activity and the product distribution, apart from slightly increasing the selectivity of iso-paraffins,which is the indication of isomerization activity. Coating of zeolite onto the iron based FTS catalyst to form acore-shell structure was intended to enhance the ease of migration of the reactant and thus increasing thecatalytic activity and shifting the product distribution towards the gasoline range. While zeolite shell has beensuccessfully coated uniformly on the iron based core using hydrothermal synthesis technique, the formation ofthick zeolite shell might have blocked the active FTS sites on the iron based catalyst to some extent and isbelieved to have contributed to the low activity of the core-shell catalyst.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.001
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.095
Threshold uncertainty score0.860

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.001
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0010.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.031
GPT teacher head0.269
Teacher spread0.238 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations1
Published2015
Admission routes1
Has abstractyes

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