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Record W1634853520 · doi:10.1089/ees.2013.0305

Recovery of Medium-Chain-Length Poly(3-Hydroxyalkanoates) from <i>Pseudomonas putida</i> KT2440 by NaOH Digestion

2014· article· en· W1634853520 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.
fundA Canadian funder is recorded on the work.

Bibliographic record

VenueEnvironmental Engineering Science · 2014
Typearticle
Languageen
FieldMaterials Science
Topicbiodegradable polymer synthesis and properties
Canadian institutionsQueen's University
FundersNatural Sciences and Engineering Research Council of Canada
KeywordsPolyhydroxyalkanoatesPseudomonas putidaDigestion (alchemy)ChemistryChromatographyNuclear chemistryPseudomonasCrystallinityLysozymeOrganic chemistryEnzymeBacteriaBiochemistryBiology

Abstract

fetched live from OpenAlex

A method for the recovery of medium-chain-length polyhydroxyalkanoate (MCL-PHA) from Pseudomonas putida KT2440 was developed using NaOH digestion. PHA purity was affected by several factors, including NaOH concentration, temperature, digestion time, and number of treatment cycles. PHA purity of about 85% was attained after 70 g/L biomass containing 66% PHA was treated with 0.2 N NaOH at 22°C±1°C for 2 h or with 0.1 N at 80°C for 15 min. However, sequential treatment of 0.2 N NaOH at 22°C±1°C for 2 h followed by 0.1 N NaOH at 80°C±1°C for 15 min produced PHA with a higher purity of 94.7% and a recovery efficiency of 88%. Under these conditions, digestion had a negligible effect on PHA molecular weight. Further treatment with lysozyme gave a purity of 98.6%. This is the first study to demonstrate that MCL-PHA of lower density and crystallinity than other classes of PHAs can be effectively recovered by alkaline digestion. This method is a greener alternative and lower safety risk than current industrial-scale solvent recovery processes.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.010
Threshold uncertainty score0.842

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.001
Scholarly communication0.0000.001
Open science0.0010.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.004
GPT teacher head0.159
Teacher spread0.155 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it