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Record W164096757 · doi:10.1007/1-4020-2396-0_27

Transport, Magnetic and Optical Properties of a Quasi-Two-Dimensional Organic Metal Based on BEDO-TTF (Bis-(Ethylenedioxy) Tetrathiafulvalene)

2006· book-chapter· en· W164096757 on OpenAlexaff
R. B. Lyubovskiǐ, S. I. Pesotskiǐ, M. Gener, Roger Rousseau, Enric Cañadell, N. Drichko, R. M. Vlasova, V. N. Semkin, Olga A. Bogdanova, E. I. Zhilyaeva, Rimma N. Lyubovskaya

Bibliographic record

VenueKluwer Academic Publishers eBooks · 2006
Typebook-chapter
Languageen
FieldMaterials Science
TopicOrganic and Molecular Conductors Research
Canadian institutionsSteacie Institute for Molecular Sciences
Fundersnot available
KeywordsFermi surfaceCondensed matter physicsChemistryEthylenedioxyMetalTetrathiafulvaleneMagnetoresistanceSpectral lineShubnikov–de Haas effectFermi levelElectronMoleculePhysicsQuantum oscillationsMagnetic fieldSuperconductivity

Abstract

fetched live from OpenAlex

Polarized reflectivity spectra, tight binding band structure calculations as well as magnetoresistance and magnetization measurements have been carried out for the new quasi-two-dimensional organic conductor β″-(BEDO-TTF)5[CsHg(SCN)4]2. Polarized reflectivity and optical conductivity spectra have shown that at low temperatures this salt exhibits metallic behaviour in the direction perpendicular to the BEDO-TTF stacks, but non-metallic behaviour in the direction parallel to the stacks. It is supposed that the non-metallic behaviour is due to the dimerization of BEDO-TTF molecules in the stacks at low temperatures. Tight binding calculations suggest that the Fermi surface can be described as containing two contributions: a closed two-dimensional portion associated with holes and a open, pseudo-one-dimensional portion associated with electrons. Shubnikov-de Haas and de Haas-van Alphen oscillations have shown that some frequencies of their complicated Furie spectra are in good agreement with the calculated Fermi surface. The other frequencies of the spectra can be well understood in the frame of the quantum interference effect.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow), Research integrity, Insufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: none
Teacher disagreement score0.424
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0010.001
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0010.000
Science and technology studies0.0000.001
Scholarly communication0.0000.000
Open science0.0010.000
Research integrity0.0010.002
Insufficient payload (model declined to judge)0.0020.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.023
GPT teacher head0.228
Teacher spread0.205 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2006
Admission routes1
Has abstractyes

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