Hydrothermal alteration and microbial sulfate reduction in peridotite and gabbro exposed by detachment faulting at the Mid‐Atlantic Ridge, 15°20′N (ODP Leg 209): A sulfur and oxygen isotope study
Bibliographic record
Abstract
Whole rock sulfur and oxygen isotope compositions of altered peridotites and gabbros from near the 15°20′N Fracture Zone on the Mid‐Atlantic Ridge were analyzed to investigate hydrothermal alteration processes and test for a subsurface biosphere in oceanic basement. Three processes are identified. (1) High‐temperature hydrothermal alteration (∼250–350°C) at Sites 1268 and 1271 is characterized by 18O depletion (2.6–4.4‰), elevated sulfide‐S, and high δ34S (up to ∼2 wt% and 4.4–10.8‰). Fluids were derived from high‐temperature (>350°C) reaction of seawater with gabbro at depth. These cores contain gabbroic rocks, suggesting that associated heat may influence serpentinization. (2) Low‐temperature (<150°C) serpentinization at Sites 1272 and 1274 is characterized by elevated δ18O (up to 8.1‰), high sulfide‐S (up to ∼3000 ppm), and negative δ34S (to −32.1‰) that reflect microbial reduction of seawater sulfate. These holes penetrate faults at depth, suggesting links between faulting and temperatures of serpentinization. (3) Late low‐temperature oxidation of sulfide minerals caused loss of sulfur from rocks close to the seafloor. Sulfate at all sites contains a component of oxidized sulfide minerals. Low δ34S of sulfate may result from kinetic isotope fractionation during oxidation or may indicate readily oxidized low‐δ34S sulfide derived from microbial sulfate reduction. Results show that peridotite alteration may be commonly affected by fluids ± heat derived from mafic intrusions and that microbial sulfate reduction is widespread in mantle exposed at the seafloor.
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How this classification was reachedexpand
Full frame machine prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.
Distilled classifier scores by category (both heads)
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.001 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.001 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".