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Record W1650937382 · doi:10.1103/physrevb.76.214427

Impurity-induced singlet breaking in<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mrow><mml:mi mathvariant="normal">Sr</mml:mi><mml:msub><mml:mi mathvariant="normal">Cu</mml:mi><mml:mn>2</mml:mn></mml:msub><mml:msub><mml:mrow><mml:mo>(</mml:mo><mml:mi mathvariant="normal">B</mml:mi><mml:msub><mml:mi mathvariant="normal">O</mml:mi><mml:mn>3</mml:mn></mml:msub><mml:mo>)</mml:mo></mml:mrow><mml:mn>2</mml:mn></mml:msub></mml:mrow></mml:math>

2007· article· lv· W1650937382 on OpenAlexaff
A. A. Aczel, G. J. MacDougall, J. A. Rodriguez‐Rivera, G. M. Luke, Peter L. Russo, A. T. Savici, Y. J. Uemura, H. A. Dabkowska, C. R. Wiebe, J.A. Janik, Hiroshi Kageyama

Bibliographic record

VenuePhysical Review B · 2007
Typearticle
Languagelv
FieldPhysics and Astronomy
TopicPhysics of Superconductivity and Magnetism
Canadian institutionsBrockhouse Institute for Materials ResearchMcMaster University
Fundersnot available
KeywordsSuperexchangeMuonMuon spin spectroscopySinglet statePhysicsCrystallographyGround stateDopingCondensed matter physicsAntiferromagnetismAtomic physicsParticle physicsChemistryExcited state

Abstract

fetched live from OpenAlex

We have performed muon spin relaxation $(\ensuremath{\mu}\mathrm{SR})$ studies on single crystals of $\mathrm{Sr}{\mathrm{Cu}}_{2}{(\mathrm{B}{\mathrm{O}}_{3})}_{2}$, a quasi-two-dimensional spin system with a spin-singlet ground state. We find evidence for two different muon sites which we associate with muons located adjacent to the two inequivalent O sites. One site, presumably located in the Cu-O-Cu superexchange path, exhibits a large increase in the frequency shift with decreasing temperature which is unaffected by the onset of the singlet ground state, indicating that the muon has perturbed the Cu-Cu interaction and created two quasifree spins. We have also performed $\ensuremath{\mu}\mathrm{SR}$ on single crystals of $\mathrm{Sr}{\mathrm{Mg}}_{0.05}{\mathrm{Cu}}_{1.95}{(\mathrm{B}{\mathrm{O}}_{3})}_{2}$, ${\mathrm{Sr}}_{0.96}{\mathrm{La}}_{0.04}{\mathrm{Cu}}_{2}{(\mathrm{B}{\mathrm{O}}_{3})}_{2}$, and ${\mathrm{Sr}}_{0.95}{\mathrm{Na}}_{0.05}{\mathrm{Cu}}_{2}{(\mathrm{B}{\mathrm{O}}_{3})}_{2}$. We have found that the frequency shifts of these doped samples are equivalent and contain three branches at low temperatures. Two of these branches map onto the branches observed in the pure sample, and so we attribute the third branch to a dopant effect. Specifically, this third branch represents the case when the muon resides at a site in the superexchange path where a local singlet cannot form due to doping. This leads to the conclusion that doping this system both in and out of the $\mathrm{Cu}\mathrm{B}{\mathrm{O}}_{3}$ planes prevents the formation of some singlets.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.001
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.020
Threshold uncertainty score0.066

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.001
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.001
Science and technology studies0.0010.000
Scholarly communication0.0010.001
Open science0.0010.000
Research integrity0.0010.001
Insufficient payload (model declined to judge)0.0200.002

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.019
GPT teacher head0.252
Teacher spread0.233 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations15
Published2007
Admission routes1
Has abstractyes

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